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Axially Chiral Spirosilanes via Catalytic Asymmetric Intramolecular Hydrosilation

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This article is published in Journal of the American Chemical Society.The article was published on 1996-12-11. It has received 110 citations till now. The article focuses on the topics: Intramolecular force.

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Citations
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Enantioselective methodologies for the synthesis of spiro compounds

TL;DR: The aim of this tutorial review is to summarize the last trends and developments reported in the literature in the enantioselective synthesis of spirocompounds.
Journal ArticleDOI

Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

TL;DR: Spirocycles provide an exciting platform to develop and understand the reactivity and selectivity for a wide variety of catalysts while affording diverse strategies to access molecules with importa...
Journal ArticleDOI

Rhodium-catalyzed asymmetric synthesis of spirosilabifluorene derivatives

TL;DR: The asymmetric synthesis of chiral spirosilabifluorene derivatives from bis(biphenyl)silanes, bearing substituents on the aromatic rings, using a rhodium catalyst with a chiral phosphine ligand is reported.
Journal ArticleDOI

Catalytic enantioselective carbon-carbon bond formation using cycloisomerization reactions

TL;DR: In this article, a review describes important recent advancements in asymmetric cycloisomerization reactions and a wide variety of catalytic and asymmetric strategies have been applied to these reactions over the past twenty years.
References
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Book

Stereochemistry of Organic Compounds

TL;DR: Stereochemistry of Alkenes Conformation of Acyclic Molecules Configuration and conformation of cyclic Molecule Stereoselective Synthesis Chiroptical Properties Chirality in Molecules Devoid of Chiral Centres as discussed by the authors.
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