Journal ArticleDOI
Barium Permanganate, Ba(MnO4)2, A Versatile and Mild Oxidizing Agent for Use Under Aprotic and Non-Aqueous Conditions
TLDR
Barium permanganate is an easily prepared, stable, and a versatile oxidation reagent as discussed by the authors, and it can be used to transform primary and secondary hydroxy compounds to their carbonyl derivatives.About:
This article is published in Tetrahedron.The article was published on 1990-01-01. It has received 16 citations till now. The article focuses on the topics: Reagent & Barium permanganate.read more
Citations
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Zinc Bismuthate Zn(BiO3)2. I. A Useful Oxidizing Agent for the Efficient Oxidation of Organic Compounds
TL;DR: Zinc bismuthate is an easily prepared and stable compound and it could be used as an oxidant in organic solvents under aprotic or in the presence of a catalytic amount of a protic solvent as discussed by the authors.
Journal ArticleDOI
Conversion of Sulfides to Their Corresponding Sulfoxides with Barium Permanganate Ba (MnO4)2 Under Non-Aquesous Condition
H. Firouzabadi,M. Seddighi +1 more
TL;DR: In this article, the authors used barium permanganate in refluxing acetonitrile to perform sulfide oxidation to their sulfoxides, which was performed with barium-peranganate.
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Enantiospecific total synthesis of (+)-tanikolide via a key [2,3]-Meisenheimer rearrangement with an allylic amine N-oxide-directed epoxidation and a one-pot trichloroisocyanuric acid N-debenzylation and N-chlorination.
TL;DR: The enantiospecific total synthesis of the δ-lactonic marine natural product (+)-tanikolide, isolated from Lyngbya majuscula, was achieved using a [2,3]-Meisenheimer rearrangement as the key reaction because it was discovered that the allylic amine N-oxide could direct the m-CPBA double-bond epoxidation to the syn position.
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Tetrakis(pyridine)silver(II) Peroxodisulfate, [Ag(py)4]S2O8, a Reagent for the Oxidative Transformations
TL;DR: Tetrakis(pyridine)silver(II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzyric carbon-hydrogen bonds to caronyl groups as discussed by the authors.
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Oxidation of benzylic hydrocarbons to carbonyl-compounds by tetrapyridinesilver(ii) peroxydisulfate ag(py)4s2o8 under nonaqueous and aprotic condition
TL;DR: In this article, different benzylic hydrocarbons are oxidized by tetrapyridinesilver(II) peroxydisulfate in refluxing acetonitrile to produce their corresponding carbonyl compounds in moderate to excellent yields.
References
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Journal ArticleDOI
Barium manganate. A versatile oxidant in organic synthesis.
TL;DR: Barium manganate is a reagent capable of oxidizing organic substrates, converting alcohols to their corresponding carbonyl compounds, aromatic amines to their respective azo compounds, hydroquinone to p-benzoquinone, benzylamine to benzaldehyde, and triphenylphosphine to its oxide in good yields as discussed by the authors.
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Solid Manganese Dioxide as an Oxidizing Agent
R. J. Highet,W. C. Wildman +1 more
TL;DR: In this article, it was shown that a higher ratio of manganese dioxide to alcohol results in a higher yield of aldehyde with a shorter reaction period, and that the effect of the solvent upon the yield noted by the previous authors is not significant.
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Oxidation with metal oxides. III. Oxidation of diamines and hydrazines with manganese dioxide
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Bis(2,2'-bipyridyl)copper(II) permanganate (BBCP): A mild and versatile oxidant in organic synthesis
TL;DR: In this paper, the preparation of bis(2,2'-bipyridyl)copper(II) permanganate (BBCP) is described, where the reagent converts alcohols to the corresponding carbonyl compounds, α-hydroxy ketones to diketones, hydroquinone to p-benzoquinone, and compounds with benzylic double bonds to benzaldehyde in high yield.
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Barium Permangante a Useful Oxidant for the Selective Deoximation of Benzylic Oximes to their Corresponding Carbonyl Compounds
TL;DR: Benzylic oximes are oxidized selectively with barium permanganate in refluxing acetonitrile and produce their corresponding carbonyl compounds in good yields as discussed by the authors.