Journal ArticleDOI
Bidentate alkene-aminocarbene complexes of chromium. Synthesis and reactivity toward alkynes
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The reaction of the aminocarbene complex (CO) 5 Cr=C(CH 3 )NHCH 2 CH=CH 2 with lithium diisopropylamide followed by methyl iodide led, to (CO, 5 Cr =C( CH 3 )N( CH 2 CH =CH 2 and, to(CO, 4 Cr = C(CH 2 )N (CH 3 ),CH 2, CH = CH 2 )About:
This article is published in Organometallics.The article was published on 1989-09-01. It has received 42 citations till now. The article focuses on the topics: Reactivity (chemistry) & Lithium diisopropylamide.read more
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Fischer Carbene Complexes in Organic Synthesis: Metal-Assisted and Metal-Templated Reactions
Karl Heinz Dötz,Joachim Stendel +1 more
TL;DR: This review concentrates on group 6 metal carbene complexes with a special focus on chromium complexes since, because of their balance of reactivity and stability combined with easy accessibility, they are the most prominent members of the Fischer carbenes and have found the broadest application.
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Fischer Carbene Complexes as Chemical Multitalents: The Incredible Range of Products from Carbenepentacarbonylmetal alpha,beta-Unsaturated Complexes.
TL;DR: Beyond doubt, the methodological arsenal of preparative organic chemistry cannot be imagined any more without the valuable transformations of the Fischer carbene complexes; it only remains to be seen whether one or other of the numerous new types of cocyclization products of these complexes can establish itself as a lead structure in the search for biologically active compounds.
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The Use of Fischer Carbene Complexes for the Preparation of Five-Membered Carbocyclic Rings
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Fischer-Carbenkomplexe als chemische Multitalente: die unglaubliche Produktpalette ausα,β-ungesättigten Carbenpentacarbonylmetall-Komplexen
TL;DR: The Fischer-Carben-Komplexe as mentioned in this paper is a formal cycloaddition of α,β-ungesattigten carbenmetall-komplexen an alkine unter CO-insertion.