Open AccessJournal Article
Bimetallic barium-titanium alcoholates and their reactions of decomposition with the formation of oxocomplexes
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This article is published in Russian Journal of Inorganic Chemistry.The article was published on 1993-01-01 and is currently open access. It has received 9 citations till now. The article focuses on the topics: Chemical decomposition & Titanium.read more
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Low-nuclearity titanium oxoalkoxides: the trititanates [Ti3O](OPri)10 and [Ti3O](OPri)9(OMe)
TL;DR: The tritinate [Ti3O](OPri)9(OMe) was isolated from the reaction of Ti(OPri),4 with water and methanol in isopropanol solution and characterized by elemental analysis, multinuclear NMR spectroscopy, and single-crystal X-ray diffraction (a = 23.295(5), b = 19.560(4), c = 18.661(4) A, β = 108.39(3)°; Z = 8 ; space group P21/c-C2h
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Tantalum(V) alkoxides : Electrochemical synthesis, mass-spectral investigation and oxoalkoxocomplexes
TL;DR: Ta(OR)5 (R = Me(1), Et(2), Bun(3)) and Ta2O(OPri)8·PriOH (4) were obtained by the anodic oxidation of metallic tantalum in absolute alcohols in the presence of LiCl (electroconductive additive) as discussed by the authors.
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Physicochemical approach to the studies of metal alkoxides
N. Ya. Turova,E. P. Turevskaya,M. I. Yanovskaya,Alexsandr I. Yanovsky,Vadim G. Kessler,D.E. Tcheboukov +5 more
TL;DR: In this article, a review of the main events in the development of metal alkoxides in Russian and summarizes the results obtained by the authors has been provided, including the analysis of solubility and vapor pressure in the M(OR)n-ROH (R Li, Mg, Ca, Sr, Ba, Tl) systems permitted the determination of the composition of the solvates formed and the optimization of the isolation conditions for distinct derivatives.
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Room temperature perovskite production from bimetallic alkoxides by ketone assisted oxo supplementation (KAOS)
B. C. Gaskins,John J. Lannutti +1 more
TL;DR: Barium titanate has been prepared at room temperature from a well-characterized crystalline barium titanium oxo alkoxide by reaction with acetone as mentioned in this paper, and the resulting crystallites are dense and perfect with an average size of approximately 85 A.
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Bimetallic alkoxides of aluminium-hafnium and aluminium-zirconium. X-ray structure of Al2Hf(OPri)10
E. P. Turevskaya,D. V. Berdyev,N. Ya. Turova,Zoya A. Starikova,A. I. Yanovsky,Yu. T. Struchkov,A. I. Belokon +6 more
TL;DR: In this paper, the existence of the only known AlM(OR) 7 species was disproved, and the results of the single crystal X-ray diffraction study of I and II were shown to be isostructural.