Journal ArticleDOI
Bimolecular Displacement Reactions. I. Reaction of endo-Norbornanol and 7-Norbornanol with Triphenylphosphine and Bromine
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This article is published in Journal of Organic Chemistry.The article was published on 1965-08-01. It has received 30 citations till now. The article focuses on the topics: Triphenylphosphine.read more
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Oxidative cleavage of silicon-carbon bonds in organosilicon fluorides to alcohols
Kohel Tamao,Toshio Kakui,Munetaka Akita,T. Iwahara,R. Kanatani,Jun-ichi Yoshida,Makoto Kumada +6 more
TL;DR: In this article, the C-Si bonds in organosilicon fluorides, K 2 (RSiF 5 ] and R n SiF 4-n, are cleaved by m-chloroperbenzoic acid (MCPBA) in DMF to give the corresponding alcohols in high yields.
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Synthesis of terminally perfluorinated long-chain alkanethiols, sulfides and disulfides from the corresponding halides
TL;DR: In this article, the authors compared the selectivity of the two classical methods based on sodium hydrogen sulfide and sodium thiosulfate and compared relatively to the selective synthesis of the title compounds.
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Structural studies on marine humus: a new reduction sequence for carbon skeleton determination
TL;DR: In this article, a new reduction sequence designed to transform polyfunctional molecules to hydrocarbons is applied to fulvic acid isolated from Sargasso Sea and coastal water, which indicates that marine lipids are important structural components and that terrestrial sources are minor.
Journal ArticleDOI
Stereospecific and Stereoselective Reactions. II. Preparation of Esters of N-Phthaloyl-α-amino Acid from Esters of α-Hydroxy Acid
TL;DR: In this paper, the authors examined the selectivity and stereospecificity of the intermolecular dehydration between alcohols and phthalimide by means of diethyl azodicarboxylate (I) and triphenylphosphine (II) for the synthesis of esters of N-phthaloyl-α-amino acid.
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The structure of triphenylphosphorus–dibromine, the first crystallographically characterised bromophosphorane, a compound which has the novel four-coordinate molecular Ph3P–Br–Br geometry
Neil Bricklebank,Stephen M. Godfrey,Anthony G. Mackie,Charles A. McAuliffe,Robin G. Pritchard +4 more
TL;DR: Triphenylphosphorus-dibromine was shown by X-ray crystallography to have a four-coordinate Ph3P-Br-Br "spoke" structure as discussed by the authors.