Journal ArticleDOI
Cation distortion isomerism in three five-coordinate (diethylenetriamine) (2,2′-bipyridylamine)copper(II) complexes
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This article is published in Inorganic and Nuclear Chemistry Letters.The article was published on 1978-01-01. It has received 16 citations till now. The article focuses on the topics: Distortion & Diethylenetriamine.read more
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Book ChapterDOI
A new look at the stereochemistry and electronic properties of complexes of the copper(II) ion
TL;DR: As a consequence of the non-spherical symmetry of the copper(II) ion, d9 configuration, and of the influence of the Jahn-Teller, and pseudo Jahn Teller effect on six-coordinate geometries, the stereochemistries of copper( II) ion are characterized by non-rigid geometry (fluxional behaviour), and ranges of distorted geometry (Plasticity Effect) The latter may be connected by a series of Structural Pathways, which may be characterised by an "Electronic Criterion of Stereochemistry
Journal ArticleDOI
Copper(ii) coordination compounds: classification and analysis of crystallographic and structural data ii. mononuclear-, hexa-, hepta-and octacoordinate compounds
TL;DR: In this paper, a review of the data for over five hundred and fifty six-, seven-and eight-coordinate Cu(II) coordination compounds is presented, where the most common ligands are O-and N-donors.
Journal ArticleDOI
Crystal structure of bis(2,2′-bipyridyl)monochlorocopper(II) tetrafluoroborate. A relook at the structural pathway of the bis(2,2′-bipyridyl)monochlorocopper(II) cation
TL;DR: The crystal structure of [Cu(bipy)2Cl]BF4(I) has been determined using diffractometer data collection as mentioned in this paper, which was solved by the heavy-atom method and successive Fourier difference syntheses.
Journal ArticleDOI
Synthesis, X-ray structure, spectroscopic and magnetic properties of [bis(4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N′,N1)-(aqua)copper(II)]bis(hydrogensulfate)
TL;DR: In this article, the synthesis, crystal structure, spectroscopic and magnetic properties of a five-coordinated mononuclear copper(II) compound with the ligand 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole (abbreviated as abpt) is reported.
Journal ArticleDOI
Copper (ii) coordination compounds: classification and analysis of crystallographic and structural data
TL;DR: In this paper, a review summarizes the data for over twelve hundred four -and five -coordinate copper(II) coordination compounds and several relationships are found and discussed, including three types of isomerism -distortion, cis-and trans-and configuration.
References
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Journal ArticleDOI
The electronic properties and stereochemistry of mono-nuclear complexes of the copper(II) ion
B.J. Hathaway,D.E. Billing +1 more
Journal ArticleDOI
Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds
TL;DR: In this paper, the WKB expression for tunneling frequencies permits correlation of these frequencies for members of homologous series of molecules, and the necessary data required are the tunneling rate for one member of the series, and structural parameters and vibrational frequencies for all members of interest.
Journal ArticleDOI
Plasticity of the coordination sphere of copper(II) complexes, its manifestation and causes
Journal ArticleDOI
The electronic properties of trigonal bipyramidal complexes of the copper(II) ion
TL;DR: In this paper, the e.s.r. and magnetic moments of trigonal bipyramidal complexes of the copper(II) ion were derived and the theoretical expressions for the g-values for a copper-II ion in a triaminotriethylamine configuration were derived, and applied only to the Cu(NH3)2Ag(SCN)3 complex.
Journal ArticleDOI
On the suggested correlation between the electronic absorption spectra and stereochemistry in [CuN5]2+ and [CuN6]2+ chromophores
TL;DR: In this paper, the diffuse reflectance spectra of a number of closely related [CuN5]2+ and [Cu6]2+) chromophores have been examined to test empirically recent statements by Hathaway and his co-workers that the electronic spectra could be used to assign structures to copper(II) compounds.
Related Papers (5)
The electronic properties and stereochemistry of mono-nuclear complexes of the copper(II) ion
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W. D. Harrison,B. J. Hathaway +1 more