Journal ArticleDOI
Cocondensation reaction of arsine and fluorine: matrix infrared spectrum of fluoroarsine
Lester Andrews,Thomas C. McInnis +1 more
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This article is published in Inorganic Chemistry.The article was published on 1991-07-01. It has received 9 citations till now. The article focuses on the topics: Arsine.read more
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Präreaktive Komplexe der Dihalogene XY mit Lewis‐Basen B in der Gasphase: eine systematische Studie der Halogen‐Analoga B⋅⋅⋅XY der Wasserstoffbrückenbindungen B⋅⋅⋅HX
TL;DR: In this article, the authors describe the abgebildeten Strukturen von Oxiran and ClF in der Gasphase, in denen B eine einfache Lewis-Base, XY ein Homo- oder Heterodihalogen-and HX ein Halogenwasserstoffmolekul ist.
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Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes
TL;DR: The available data on main group (Groups 12-18) Lewis acid base, donor-acceptor, charge transfer and van der Waals complexes stabilised by matrix isolation techniques are presented, tabulated and evaluated in conjunction with data from complementary gas phase experiments and computational chemistry as discussed by the authors.
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Chemistry of the Tetraselenomolybdate Anion: Syntheses, Spectroscopic Results, and Structural Characterizations of Polynuclear Mo−Cu−Se Compounds Containing Thiolate Ligands
TL;DR: In this paper, a DMF solution of [Et4N]2[MoSe4] was found to react with 3 equiv of CuCl in the presence of NaS2CNR2 [R2 = Et2, C5H10, (PhCH2)2, Me2] to give a series of Mo−Cu−Se compounds.
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A Computational Study of Chalcogen-containing H2X…YF and (CH3)2X…YF (X=O, S, Se; Y=F, Cl, H) and Pnicogen-containing H3X′…YF and (CH3)3X′…YF (X′=N, P, As) Complexes
TL;DR: A computational study was undertaken for the model complexes H2 X…YF and (CH3 )2 X….YF, and H3 X'…Yf and ( CH3 )3 X’…yF, finding the binding is especially strong for the complexes containing F2, implying significant chemical bonding between the interacting molecules.
Journal ArticleDOI
Mercury-fluorine interactions: a matrix isolation investigation of Hg...F2, HgF2 and HgF4 in argon matrices.
John F. Rooms,Antony V. Wilson,Ian Harvey,Adam J. Bridgeman,Adam J. Bridgeman,Nigel A. Young +5 more
TL;DR: Hg L(3)-edge EXAFS has provided the first experimental value of 1.94(2) A for the Hg-F bond length in HgF(2), which is in excellent agreement with the computational values incorporating relativistic effects.