Journal ArticleDOI
Conformational and stereochemical consequences of uniparticulate electrophilic additions to cis-bicyclo[6.1.0] nonatrienes. Reactions with tetracyanoethylene
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This article is published in Journal of the American Chemical Society.The article was published on 1973-07-01. It has received 11 citations till now. The article focuses on the topics: Tetracyanoethylene.read more
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Darstellung des cis,cis,cis,trans-[9]Annulen-Anions
TL;DR: In this paper, the authors investigated the stability of the all-cis-anion 3 and showed that it can be formed directly from the isomeric 9-syn-methoxy and 9-synthesis-and-chloro-bicyclo.
Journal ArticleDOI
Synthesis and study of select heterocycles
TL;DR: In this paper, the synthesis and subsequent study of a variety of π heterocycles with particular emphasis placed on the recognition of key steric and electronic factors controlling the development of heteroaromaticity as well as its less conventional variants, heterohomoarromaticity and heterobicyclo-caromaticity.
Journal ArticleDOI
Computational study of 1,3-dithiane 1,1-dioxide (1,3-dithiane sulfone). Description of the inversion process and manifestation of stereoelectronic effects on 1JC-H coupling constants.
Rafael Notario,María Victoria Roux,Gabriel Cuevas,Julio Cardenas,Verónica Leyva,Eusebio Juaristi +5 more
TL;DR: A description of the inversion-topomerization process of 1,3-dithiane sulfone is presented and Calculations show that two transition states are associated with inversion and three more with topomerization.
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Reactions of the Cyclooctatetraenyl Dianion with gem-Dihalides. The Preparation of Derivatives of Bicyclo [6.1.0]nonatriene. Synthesis of the Cyclononatetraenyl Anion
Thomas J. Katz,Peter J. Garratt +1 more
Evidence for cis,cis,trans,cis-1,3,5,7-cyclononatetraene in the thermal bond relocation of cis-bicyclo[6.1.0]nona-2,4,6-triene
A. G. Anastassiou,R. C. Griffith +1 more