Journal ArticleDOI
Consistent size dependency of core-level binding energy shifts and single-electron tunneling effects in supported gold nanoclusters
Taizo Ohgi,Daisuke Fujita +1 more
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This article is published in Physical Review B.The article was published on 2002-09-19. It has received 78 citations till now. The article focuses on the topics: Scanning tunneling spectroscopy & Nanoclusters.read more
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Size dependence of nanostructures: Impact of bond order deficiency
Chang Q. Sun,Chang Q. Sun +1 more
TL;DR: The BOLS correlation mechanism has been initiated and intensively verified as discussed by the authors, which has enabled the tunability of a variety of properties of a nanosolid to be universally reconciled to the effect of bond order deficiency of atoms at sites surrounding defects or near the surface edges of the nano-material.
Journal ArticleDOI
Thermo-mechanical behavior of low-dimensional systems: The local bond average approach
TL;DR: Local bond average (LBA) as mentioned in this paper has been proposed to compare the measurable quantities of a specimen to the identities of its representative bonds and the energetic responses of these bonds (bond nature, order, length and strength) to external stimuli, such as changes in temperatures and coordination environments.
Journal ArticleDOI
Surface and nanosolid core-level shift: Impact of atomic coordination-number imperfection
TL;DR: In this paper, a correlation mechanism was proposed to unify the effects of surface relaxation and nanosolid formation on the core-level binding energy shift into the atomic-coordination number imperfection.
Journal ArticleDOI
The d-band structure of Pt nanoclusters correlated with the catalytic activity for an oxygen reduction reaction
Eishiro Toyoda,Ryosuke Jinnouchi,Tatsuya Hatanaka,Yu Morimoto,Kei Mitsuhara,Anton Visikovskiy,Yoshiaki Kido +6 more
TL;DR: In this article, the d-band center of Pt nanoclusters was found to move toward the Fermi level with decreasing cluster size, as predicted by the first-principles calculations using linear combinations of pseudoatomic orbitals and norm-conserved pseudopotentials.
Journal ArticleDOI
Coordination-Resolved Electron Spectrometrics
Xinjuan Liu,Xi Zhang,Maolin Bo,Lei Li,Hongwei Tian,Yanguang Nie,Yi Sun,Shiqing Xu,Yan Wang,Weitao Zheng,Chang Q. Sun +10 more
TL;DR: This paper aims to provide a history of low-Dimensional Materials and Application Technologies from 1989 to 2000, a period chosen in order to explore its roots as well as specific cases up to and including the Yangtze River floods of 1997.
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