Journal ArticleDOI
Conversion of cyclic trithiocarbonates to thioacetals, including 1,3-dithiane, by reduction with diisobutylaluminium hydride (dibal)
Ulrich Jordis,Manfred Rudolf +1 more
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TLDR
In this paper, a new synthetic pathway was exploited for the preparation of several Umpolung reagents, including 1,3-dithiane, and an efficient isolation of sodium trithiocarbonate was described.Abstract:
Cyclic trithiocarbonates can be desulfurized with diisobutylaluminium hydride (DIBAL) to form the corresponding thioacetals. This new synthetic pathway was exploited for the preparation of several Umpolung reagents, including 1,3-dithiane. An efficient isolation of sodium trithiocarbonate is described.read more
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An efficient one-pot access to trithiocarbonate-tethered peptidomimetics
TL;DR: A simple protocol for the synthesis of a new class of trithiocarbonate-linked peptidomimetics and neoglycosylated amino acids is described, which upon reaction with appropriate halides afforded dipeptidomIMetics in good yields.
Journal ArticleDOI
An Efficient, One-Pot Synthesis of S-Alkyl Thiocarbamates from the Corresponding Thiols Using the Mitsunobu Reagent
TL;DR: In this article, a Mitsunobu-based protocol was developed for the synthesis of trithiocarbonates from primary, secondary and tertiary thiols using carbon disulfide.
Journal ArticleDOI
An efficient, one-pot synthesis of trithiocarbonates from alcoholic tosylates using the Cs2CO3/CS2 system
TL;DR: In this paper, a single-step protocol for the preparation of symmetric trithiocarbonates from a corresponding variety of primary, secondary, and tertiary alcoholic tosylates using the Cs2CO3/CS2 system was developed.
Journal ArticleDOI
Benzothiadiazole vs. iso-Benzothiadiazole: Synthesis, Electrochemical and Optical Properties of D-A-D Conjugated Molecules Based on Them.
Nikita S. Gudim,Ekaterina A. Knyazeva,L. V. Mikhal’chenko,Ivan S. Golovanov,Vadim V. Popov,Natalia V. Obruchnikova,Oleg A. Rakitin +6 more
TL;DR: In this paper, the Stille reaction was used to synthesize 6 new π-spacer-acceptor-π spacer type compounds, including 4,7-dibromobenzo[d][1,2,3]thiadiazole and 2,2′-bithiophene fragment.
Journal ArticleDOI
Review of the organic trithiocarbonates synthesis
TL;DR: In this article, various reported methods in the literature for the synthesis of symmetrical, unsymmetrical, and cyclic trithiocarbonates are discussed, as well as their applications in industrial and medical chemistry.
References
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Bull. Soc. Chim. Fr.
G. Hugel,G. Ourisson,J. Bye,J Miquel,D. P. Funeriu,Y He,H Bister,J-M Lehn,M Mousseron,J. M. Kamenka,Darvich +10 more
Book
Interpretation of Mass Spectra
TL;DR: In this paper, the basic mechanism of ion fragmentation is described and a theory of unimolecular Ion Decompositions is proposed, along with a detailed model of the mass spectrum of common compound classes.
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The Aldrich library of NMR spectra
TL;DR: The Aldrich library of NMR spectra as mentioned in this paper, the Aldrich NMR library of spectra spectra, and the A.A. Aldrich Library of NMRI spectra.
Journal ArticleDOI
Thion‐ und Dithioester, XXIV. Synthese von Tetrathiooxalestern
TL;DR: In this article, the photochemische Decarbonylierung von 4,5-Bis(methylthio)-1,3-dithiol-2-on (3a) liefert Dimethyl-tetrathiooxalat (11a), das in Losung mit seinem [4 + 2]-Dimeren 13 im Gleichgewicht steht.