Journal ArticleDOI
Crystal structure and emission spectrum of tris(nitrato)-1,4,7,10-tetraozacyclododecane-Europium(III)
TLDR
In this article, the crystal and molecular structure of the Europium(III) ion was determined from single crystal X-ray diffraction and the structure was solved by Patterson and Fourier techniques and refined by least-squares to a final conventional R value of 0.079.About:
This article is published in Inorganica Chimica Acta.The article was published on 1982-01-01. It has received 45 citations till now. The article focuses on the topics: Monoclinic crystal system & Crystal structure.read more
Citations
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Journal ArticleDOI
Lanthanide luminescence for functional materials and bio-sciences
TL;DR: This critical review describes the latest developments in the sensitization of near-infrared luminescence, "soft" luminescent materials (liquid crystals, ionic liquids, ionogels), electroluminescentmaterials for organic light emitting diodes, with emphasis on white light generation, and applications in luminecent bio-sensing and bio-imaging based on time-resolved detection and multiphoton excitation.
Journal ArticleDOI
Luminescence and structure of europium compounds
TL;DR: In this article, Europium complexes in the +3 oxidation state, with coordination numbers six, seven, eight, nine and ten, were studied by X-ray structural analyses and an attempt was made to correlate the results with the emission spectrum interpretation.
Book ChapterDOI
Lanthanide ion luminescence in coordination chemistry and biochemistry
TL;DR: In this paper, a synthese relatif aux proprietes de luminescence des complexes de lanthanide avec divers coordinats: β-dicetones, aminoacides, systemes muscellaires, macrocycles, nucleotides, proteines et enzymes.
Journal ArticleDOI
Rare earth complexes with neutral macrocyclic ligands
TL;DR: Stoechiometrie, proprietes magnetiques et structurales. as discussed by the authors, en solution des complexes des ions Ln(III); constantes de stabilite, constantes of stabilite
Journal ArticleDOI
Luminescent Bimetallic Lanthanide Bioprobes for Cellular Imaging with Excitation in the Visible‐Light Range
Emmanuel Deiters,Bo Song,Anne-Sophie Chauvin,Caroline Vandevyver,Frédéric Gumy,Jean-Claude G. Bünzli +5 more
TL;DR: Examination of data for seven Eu(III) and Tb( III) bimetallic helicates point to shortcomings in the phenomenological rules of thumb between the energy gap DeltaE((3)pipi*-(5)D(J)) and the sensitisation efficiency of the ligands.
References
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Journal ArticleDOI
Fluorescence spectra and lifetime measurements of aqueous solutions of europium nitrate and perchlorate
TL;DR: The existence of inner-sphere complexation or ion-pair formation between C104- and Ln(II1) is questionable as discussed by the authors, but the existence of the inner-space complexes is doubtful.
Journal ArticleDOI
Cooperative vibronic spectra involving rare earth ions and water molecules in hydrated salts and dilute aqueous solutions
TL;DR: In this paper, a radiative transition involving the simultaneous electronic transition of a Tb3+ ion and vibrational transition of nearby water molecule gives rise to these bands, based on an electrostatic coupling model, explain the intensities of the cooperative vibronic transitions.
Journal ArticleDOI
Vibrational Spectra of Anhydrous Lanthanum, Europium, Gadolinium, and Dysprosium Nitrates and Oxinitrates
TL;DR: In this paper, the low frequency region of the spectra reflects the cubic structure of these compounds and the vibrational frequencies of the nitrato group are consistent with a bidentate nitrate of C2v symmetry.
Journal ArticleDOI
The structure of [(C6H5)4As]2[Eu(NO3)5]
TL;DR: The structure of the title compound was solved from single crystal X-ray diffractometer data by Patterson and Fourier methods, and refined by least-squares to conventional RF = 0.046 for 2504 independent observed reflections.