Journal ArticleDOI
Crystal structure of the copper(I) iodide–pyridine (1/1 ) tetramer
Colin L. Raston,Allan H. White +1 more
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TLDR
The crystal structure of the copper(I) iodide pyridine adduct has been determined by X-ray diffraction at 295 K and refined by least squares to R 0.057 for 2 710 "observed" reflections as mentioned in this paper.Abstract:
The crystal structure of the copper(I) iodide pyridine adduct has been determined by X-ray diffraction at 295 K and refined by least squares to R 0.057 for 2 710 ‘observed’ reflections. Crystals are orthorhombic, space group P212121, with a= 16.032(6), b= 15.510(2), and c= 11.756(3)A. The asymmetric unit is Cu4I4py4, based on the well-known tetrahedral tetrameric Cu4I4 unit, with Cu–N 2.04, Cu–I 2.70, and Cu–Cu 2.69 A; the latter distance is much shorter than in the analogous complexes formed with phosphine and arsine ligands.read more
Citations
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Journal ArticleDOI
Light-Emitting Self-Assembled Materials Based on d(8) and d(10) Transition Metal Complexes.
Journal ArticleDOI
Photoluminescence Properties of Multinuclear Copper(I) Compounds.
Journal ArticleDOI
Near-infrared phosphorescence: materials and applications
TL;DR: This review describes the overall progress made in the past ten years on NIR phosphorescent transition-metal complexes including Cu(I), Cu(II), Cr(III), Re(I, Re-I), Re-III, Ru(II) and Au(I) complexes, with a primary focus on material design complemented with a selection of optical, electronic, sensory, and biologic applications.
Book ChapterDOI
Photochemistry and Photophysics of Coordination Compounds: Copper
TL;DR: In this paper, the authors compare the properties of copper compounds and clusters and point out the limited significance of Cu(II) compounds in terms of photophysical properties, pointing out the criteria by which it is now possible to successfully design highly emissive [Cu(NN)2]- compounds, a rather elusive goal for a long time.
Journal ArticleDOI
Copper(I) halides: A versatile family in coordination chemistry and crystal engineering
Rong Peng,Mian Li,Dan Li +2 more
TL;DR: The copper(I) halide aggregates represent a versatile family in coordination chemistry and crystal engineering and have been intensively investigated in the last three decades because of their structural and luminescent uniqueness as discussed by the authors.
Related Papers (5)
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