Journal ArticleDOI
Détermination des constantes thermodynamiques d'équilibres en solution par calorimétrie à conduction et flux de réactif: I. Description de la méthode
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In this article, an injection apparatus attached to the two elements of a conduction microcalorimeter allows measurement of the thermal change arising from displacement of the equilibria in the liquid phase.About:
This article is published in Thermochimica Acta.The article was published on 1975-03-01. It has received 8 citations till now.read more
Citations
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Simultaneous determination of equilibrium constants and enthalpy changes by titration calorimetry: Methods, instruments, and uncertainties.
TL;DR: Methods for quantitative comparison of the capabilities of calorimeters for simultaneous determination of equilibrium constants and enthalpy changes, for determining optimal experimental conditions, and for assessing the effects of systematic and random errors on the accuracy and precision of equilibrium variables determined by this method are reported.
Journal ArticleDOI
The development of a continuous isothermal titration calorimetric method for equilibrium studies.
Natalia Markova,Dan Hallén +1 more
TL;DR: Computer simulations show that the dynamic range for determination of equilibrium constants can be increased by three orders of magnitude compared to that of classical ITC, making it possible to determine high affinities.
Journal ArticleDOI
Medium and Alkyl Chain Effects on the Protonation of Dicarboxylates in NaCl(aq) and Et4NI(aq) at 25°C
TL;DR: In this article, the authors report the thermodynamic parameters for the protonation of a homologous series of linear dicarboxylates having the molecular formula, HOOC-(CH 2 ) n -COOH, with n = 0 - 7 (n = 0 oxalate; n = 1 malonate, n = 2 succinate; N = 3 glutarate; N.
Journal ArticleDOI
Supramolecular complexes: Determination of stability constants on the basis of various experimental methods
TL;DR: In this article, the stability constants and formation enthalpies of supramolecular complexes of crown ethers and their cyclic and acyclic analogues are determined on the basis of experimental data obtained by different physicochemical methods in terms of a general approach developed and implemented in the ChemEqui software package.
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Développement du domaine d'application de la calorimétrie à conduction et de l'analyse calorimétrique différentielle en thermodynamique et en cinétique
J.P. Dubes,M. Barres,H. Tachoire +2 more
TL;DR: In this article, the authors reported first results concerning the simultaneous determination of equilibrium constants and enthalpies of reaction by titration conduction microcalorimetry, and described an electronic on-line corrector.
References
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Determination of equilibrium constants by titration calorimetry: Part I. Introduction to titration calorimetry
TL;DR: The titration calorimetry (TC) method as discussed by the authors can be used in any solvent to determine equilibrium constants for proton ionization and metal ion interactions over a large pH range for simple and complex equilibria.
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Entropy Titration. A Calorimetric Method for the Determination of ΔG, ΔH, and ΔS from a Single Thermometric Titration1a,b
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A Calorimetric Procedure for Determining Free Energies, Enthalpies, and Entropies for the Formation of Acid-Base Adducts
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Entropies of dissociation of some moderately strong acids
Joseph L. Kurz,James M. Farrar +1 more