Donor acceptor reactions of titanium tetrachloride with formamide and n,n-dimethyl formamide
TLDR
Coordination complexes of titanium tetrachloride with formamide and N,N-dimethyl formamide have been found in this article, and all the complexes can be explained through a co-ordination number of 6 for titaniu...Abstract:
Co-ordination complexes of titanium tetrachloride with formamide and N,N-dimethyl formamide have been prepared. All the complexes found are explained through a co-ordination number of 6 for titaniu...read more
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Journal ArticleDOI
Structure of donor-acceptor complexes. VIII. Complexes of Lewis acids with ketones
TL;DR: Complexes of the Lewis acids, sulphur trioxide, antimony (V) chloride, tin (IV) chloride and aluminium (III) chloride with formamide, acetamide, benzamide,acetanilide and benzanilide have been studied for elucidating their structure.
Journal ArticleDOI
Coordination complexes of titanium (iv) halides: iii. preparation and infrared spectra of the complexes of titanium tetrachloride with urea, thiourea, and some of their derivatives
TL;DR: The following coordination complexes of titanium (IV) have been prepared: TiCl4•2CO(NH2)2, TiCl 4•CO(NHC6H5)2 and 2TiCl4-CSN(C6H 5)2; their infrared spectra have been measured and their molecular weight determined.
Journal ArticleDOI
The coordination chemistry of scandium
Gordon A. Melson,Robert W. Stotz +1 more
TL;DR: In this paper, introducectron complexes wrth oxygen donor hgands (1) Neutral oxygen donor Hgands(it) @-Drketonates (tn) Carbovyiates (IV) Alcohoiates (v) Hydrovoscandates Complexes wrft mtrogen donor hgsands (I) Ammoma (II) Primary, secondary and terttary ammes Complexs wrth mtrogen and oxygen donorHgands Hahde complexes Mnceilaneous compIexcs Summary References 133 I34 134 137 I
Journal ArticleDOI
Co-ordination complexes of group (IV) halides Preparation and infrared spectra of the complexes of group (IV) halides with diamides of α, w-dicarboxylic acids and dithio-oxamide as ligands
S.C. Jain,R. Rivest +1 more
TL;DR: In this article, a comparative study of the donor ability of the oxygen and the sulphur atoms in the oxamide and the dithio-oxamide complexes was made, and it was found that the diamides co-ordinate to the metal atom through the oxygen of the carbonyl group whereas the Doxamide molecule coordinates through the nitrogen of the amino group.
Journal ArticleDOI
COORDINATION COMPLEXES OF GROUP (IV) HALIDES: PREPARATION AND INFRARED SPECTRA OF COORDINATION COMPOUNDS OF TITANIUM TETRACHLORIDE, TITANIUM TETRABROMIDE, ZIRCONIUM TETRACHLORIDE, AND TIN TETRACHLORIDE WITH α,ω-DINITRILES AS LIGANDS
Sumer Chand Jain,Roland Rivest +1 more
TL;DR: Coordination complexes between dinitriles of dicarboxylic acids and tetrahalides of titanium, zirconium, or tin have been obtained as mentioned in this paper.
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Infrared Absorption Spectra of Inorganic Coördination Complexes. XIV. Infrared Studies of Some Metal Thiourea Complexes1a
Journal ArticleDOI
Infrared Spectrum and Thermodynamic Functions of Formamide
TL;DR: In this article, the infrared spectra of formamide in the vapour and liquid states, and in solutions in CHCl3, CCl4, CH3CN, H2O, and D2O were observed between 650 cm −1 and 3800 cm-1.