Journal ArticleDOI
Effect of dichloromethane on the molecular complexes of tetracyanoethylene
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This article is published in Journal of the American Chemical Society.The article was published on 1970-05-01. It has received 16 citations till now. The article focuses on the topics: Tetracyanoethylene & Dichloromethane.read more
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Solvent effect on the charge transfer complex of oxatomide with 2,3-dichloro-5,6-dicyanobenzoquinone.
TL;DR: The donor oxatomide is found to form stable 1:1 stoichiometric complex with DDQ and the stoichiometry was unaffected by change in polarity of the solvent studied, so the studied complex is reasonably stable and exothermic in nature.
Journal ArticleDOI
Multiple Charge‐Transfer Transitions in Alkylbenzene‐TCNE Complexes
TL;DR: In this paper, the experimental CT-hand profiles for the complexes in solution and in the gas phase are deconvoluted into two (theoretically expected) CT-subbands, furnishing accurate energies of the first and second CT-state of thc systems.
Journal ArticleDOI
Charge transfer and fluorescence behaviour of hexylamine and 7,7,8,8-tetracyanoquinodimethane in compartmentalized (reverse micelle and microemulsion) and non-aqueous environments
TL;DR: In this article, a 1:1 charge transfer complex between hexylamine (HA) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the fluorescence behaviour of the transfer complex were studied in non-aqueous solvents (dichloromethane, chloroform, carbon tetrachloride, heptane, iso-octane, decane and cyclohexane) and in sodium bis(2-ethyl-hexyl)sulphosuccinate (A
Journal ArticleDOI
Photoluminescence Enhancement of CdSe and CdSe–ZnS Nanocrystals by On‐Surface Ligand Modification
Marek Oszajca,Marek Oszajca,Christophe Lincheneau,Matteo Amelia,Christian Schäfer,Konrad Szaciłowski,Konrad Szaciłowski,Alberto Credi +7 more
TL;DR: In this paper, the authors investigated the spectroscopic properties of CdSe and ZnS nanocrystal quantum dots (QDs) in the presence of the electron acceptor tetracyanoethene (TCNE) in organic solution.
Journal ArticleDOI
Solvent effect on the charge-transfer absorption of molecular electron-donor-acceptor complexes
I. Deperasinska,J. Prochorow +1 more
TL;DR: In this paper, the influence of solvent polarity on spectroscopic and thermodynamic properties of molecular electron-donor-acceptor (EDA) complexes is discussed, and it is shown that the ground state of EDA complex is destabilized with increasing polarity of solvent and this is due to the decrease of energy of electrostatic interactions within the complex.
Related Papers (5)
Cyanocarbon Chemistry. II.1 Spectroscopic Studies of the Molecular Complexes of Tetracyanoethylene
R. E. Merrifield,W. D. Phillips +1 more