Journal ArticleDOI
Electrochemical oxidations of complexes of rhenium(II) containing metal-metal triple bonds. Synthesis and characterization of paramagnetic cations of the type [Re2X4(PR3)4]+, where X = chlorine or bromine, possessing metal-metal bonds of order 3.5
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This article is published in ChemInform.The article was published on 1978-10-17. It has received 6 citations till now. The article focuses on the topics: Rhenium & Triple bond.read more
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Epr evidence for related electronic structures of α-diimine complexes with [Ru(bpy) 2 ] 2+ and re(CO) 3 (halide) fragments
W. Kaim,S. Kohlmann +1 more
TL;DR: In this paper, low-lying unoccupied orbitals of the fragments Re(CO)3 X,XCl, Br, are inferred from EPR spectroscopy of mono-and di-nuclear complexes with the singly reduced α-diimine ligands 2,2'-dipyridine and azo-2,2su' -bipyrine.
Journal ArticleDOI
Spectroscopic and quantum theoretical studies of species with metal-to-metal bonus
TL;DR: In this paper, the results of SCF-Xa-SW calculations for the [Re 2 Cl 8 ] 2− ion, including relativistic corrections, are presented.
Journal ArticleDOI
Trioxorhena(VII)carborane Anion and Its Methyl-Substituted Analogue: Synthesis, Structure, DFT, and Catalytic Studies
TL;DR: In this paper, the synthesis and characterization of trioxorhena(VII)carborane [Bu4N][(η1-C2B9H11)ReO3] (1a) and its methyl-substituted analogue [Bu 4N] [(7,8-Me2-η 1-C 2B9 H11) ReO3 ] (1b) are reported.
Journal ArticleDOI
Heterogeneous electron-transfer kinetics for some multiply bonded dirhenium complexes
TL;DR: In this paper, the authors explore the possible dependence of k ex ob upon the known differences in the structural changes accompanying electron transfer, and show that the reactivity trends appear to be mainly a consequence of differences in electrostatic work terms at the metal/solution interface.
Journal ArticleDOI
Isolation of the complexes (n-Bu4N)2[(Re2Cl7)2{μ-(LL)}], where LL = Ph2PCCPPh2 or trans-Ph2PCHCHPPh2. The first examples of quadruply bonded dirhenium(III) anions of the type [Re2Cl7L]−
TL;DR: In this article, the bidentate bridging phosphine ligands (LL) = Ph 2 PCCPPh 2 or trans -Ph 2 PCHCHPPh 2 in methanol-conc. HCl gave the first examples of quadruply bonded dirhenium(III) anions of the type [Re 2 Cl 7 L].
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Journal ArticleDOI
Electrochemical oxidations of complexes of rhenium(II) containing metal-metal triple bonds. Synthesis and characterization of paramagnetic cations of the type [Re2X4(PR3)4]+, where X = chlorine or bromine, possessing metal-metal bonds of order 3.5
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