Journal ArticleDOI
Electron spin resonance spectra of tetragonal chromium(III) complexes. I. trans-[Cr(NH3)4XY]n+ and trans-Cr(py)4XY]n+ in frozen solutions and powders. Correlation between zero-field splittings and ligand field parameters via complete d-electron calculations
Erik. Pedersen,Hans Toftlund +1 more
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This article is published in Inorganic Chemistry.The article was published on 1974-07-01. It has received 90 citations till now. The article focuses on the topics: Ligand field theory & Tetragonal crystal system.read more
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Multi-frequency, high-field EPR as a powerful tool to accurately determine zero-field splitting in high-spin transition metal coordination complexes
TL;DR: A review of the application of electron paramagnetic resonance at multiple, high frequencies (95-700 GHz) and at correspondingly high magnetic fields (up to 25 T) is given in this article.
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Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation Chemistry
TL;DR: Recent advances in the study of the Oxygen Evolving Complex (OEC) of Photosystem II (PSII) include structural information attained from several X-ray crystallographic and spectroscopic investigations that offer better insight into the possible pathways used by PSII to drive photosynthetic water oxidation catalysis.
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Photolysis of cis- and trans-[FeIII(cyclam)(N3)2]+ Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species
TL;DR: In this paper, the reaction of cis-[FeIII(cyclam)Cl2]Cl in acidic H2O/CH3OH or CH3CN/H2O mixtures with NaN3 at 50 °C produced upon addition of NaClO4 or NaPF6 the complex trans-FeIII (cyclam)(N3)2] ClO4 (1a) or the hexafluorophosphate salt 1b, whereas at −18 °C the same reaction produced cis-(FeIII,cyclam = 1,4,
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Magnetic anisotropy of the antiferromagnetic ring [Cr8F8Piv16].
Joris van Slageren,Roberta Sessoli,Dante Gatteschi,Andrew A. Smith,Madeleine Helliwell,Richard E. P. Winpenny,Andrea Cornia,Anne-Laure Barra,Aloysius G. M. Jansen,Eva Rentschler,Grigore A. Timco +10 more
TL;DR: The excellent agreement between the experimental and the theoretical results show the validity of the used methods for the analysis of the magnetic anisotropy in antiferromagnetic CrIII rings.
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The relation between ligand structures, coordination stereochemistry, and electronic and thermodynamic properties
TL;DR: A survey of models can be found in this article, where the authors present a survey of shape, geometry, and physics models for shape interpretation and prediction, as well as the background and background information.