Enantioselective addition of diethylzinc to benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols

doi:10.1016/S0040-4039(01)81300-9

Journal ArticleDOI

Enantioselective addition of diethylzinc to benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols

Nobuki Oguni, +1 more

- 01 Jan 1984 -

Tetrahedron Letters

- Vol. 25, Iss: 26, pp 2823-2824

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TLDR

The reaction of diethylzinc with benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols in toluene at room temperature gave optically active 1-phenylpropan-1ol almost quantitatively in ∼, 50% ee as discussed by the authors.

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This article is published in Tetrahedron Letters.The article was published on 1984-01-01. It has received 296 citations till now. The article focuses on the topics: Diethylzinc & Benzaldehyde.

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Catalytic Asymmetric Organozinc Additions to Carbonyl Compounds

Lin Pu, +1 more

- 14 Mar 2001 -

Chemical Reviews

TL;DR: These studies on macromolecular chiral catalysts demonstrate that these materials are potentially very useful for practical applications and can also be preserved in the rigid and sterically regular polymer provided the catalytically active species of the monomer catalyst is not its aggregate.

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