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Journal ArticleDOI

Evaluation of a Primary Amine-Functionalized Ion-Exchange Resin for CO2 Capture

TLDR
In this paper, a primary amine functionalized polymeric ion exchange resin (Lewatit VP OC 1065, Lanxess) was evaluated for use in CO2 capture applications.
Abstract
A primary amine-functionalized polymeric ion-exchange resin (Lewatit VP OC 1065, Lanxess) was evaluated for use in CO2 capture applications. The polymeric resin was characterized by SEM, DRIFTS-IR, N2 adsorption isotherms, and packed bed sorption measurements to determine some of the characteristic properties of the resin. Capture capacities ranging from 1.85 to 1.15 mol CO2/kg sorbent were obtained in a packed bed reactor exposed to 10 vol % CO2 in N2 at adsorption temperatures ranging from 30 to 70 °C. The capture capacity of the resin was stable over 18 adsorption/regeneration cycles. The resin was evaluated through thermogravimetric analysis to have a low moisture adsorption (1.5 mol H2O/kg sorbent). It is possible to completely regenerate the resin under 1 atm of CO2 at 200 °C.

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Recent advances in solid sorbents for CO2 capture and new development trends

TL;DR: In this article, the authors organize the CO2 sorbents according to their working temperatures by classifying them as such: (1) low-temperature ( 400 °C), since the sorption capacity, kinetics, recycling stability and cost are important parameters when evaluating a sorbent.
Book

Negative Emissions Technologies and Reliable Sequestration: A Research Agenda

TL;DR: In this paper, negative emissions technologies (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change, and the benefits, risks, and sustainable scale potential for NETs and sequestration are assessed.
Journal ArticleDOI

Polyethylenimine-Impregnated Resin for High CO2 Adsorption: An Efficient Adsorbent for CO2 Capture from Simulated Flue Gas and Ambient Air

TL;DR: This spherical and stable HP20/PEI-50 adsorbent with high and fast CO2 adsorption exhibits a very promising application in CO2 capture from flue gas and ambient air.
Journal ArticleDOI

A comparative review between amines and ammonia as sorptive media for post-combustion CO2 capture

TL;DR: In this paper, the authors provided an in-depth discussion regarding the two comparable control technologies, i.e., the amine- vs. ammonia-based capture approaches; ammonia has lower energy costs than monoethanolamine (MEA).
Journal ArticleDOI

Electrochemical carbon dioxide capture to close the carbon cycle

TL;DR: In this article, the authors summarized main parameters governing electrochemical pH-swing processes and put the concept in the framework of available worldwide capture technologies, and provided recommendations for further improvements.
References
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Journal ArticleDOI

Amine Scrubbing for CO2 Capture

TL;DR: Amine scrubbing has been used to separate carbon dioxide (CO2) from natural gas and hydrogen since 1930 and is ready to be tested and used on a larger scale for CO2 capture from coal-fired power plants.
Book

Properties of Polymers: Their Correlation with Chemical Structure; their Numerical Estimation and Prediction from Additive Group Contributions

Van Krevelen
TL;DR: The fourth edition of as discussed by the authors extends coverage of critical topics such as electrical and magnetic properties, rheological properties of polymer melts, and environmental behavior and failure, and discusses liquid crystalline polymers across chapters 6, 15 and 16 for greater breadth and depth of coverage.
Journal ArticleDOI

Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable of capturing CO2 reversibly.

TL;DR: Carbon dioxide adsorption from a simulated flue gas stream was successfully performed with a hyperbranched aminosilica (HAS) material, showing the stability of the organic groups covalently bound to the silica support compared to those made by physisorbed methods.
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