Journal ArticleDOI
Evidence of unequal vinyl group reactivity in copolymerization/crosslinking reactions of mono- and divinyl comonomers
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In this paper, a kinetic model was developed for the copolymerization/cross-linking reaction of a monovinyl and a divinyl monomer, which incorporates initiation, propagation, chain transfer and termination reactions.About:
This article is published in Polymer.The article was published on 1987-05-01. It has received 15 citations till now. The article focuses on the topics: Copolymer & Monomer.read more
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Book ChapterDOI
Microgels-Intramolecularly Crossünked Macromolecules with a Globular Structure
TL;DR: In this paper, the most important structural characteristic of crosslinked polymers, the crosslink density, could mostly be determined by indirect methods only, or was expressed relatively by the fraction of crosslinking monomers used in the synthesis.
Journal ArticleDOI
Solid-phase organic synthesis: a critical understanding of the resin.
Andrew R. Vaino,Kim D. Janda +1 more
Journal ArticleDOI
Thirteen decades of peptide synthesis: key developments in solid phase peptide synthesis and amide bond formation utilized in peptide ligation
TL;DR: This review provides an overview of the literature concerning the most important advances in the chemical synthesis of proteins and peptides covering the period from 1882 to 2017 and focuses on the discovery and development of peptide ligation.
Journal ArticleDOI
Kinetic Gelation model predictions of crosslinked polymer network microstructure
TL;DR: In this article, a kinetic gelation model was used to predict the complex network structures that arise in the high crosslinking regime of homopolymerizations and copolymerizations of multifunctional monomers.
Journal ArticleDOI
Solvation of polymers as model for solvent effect investigation: proposition of a novel polarity scale
TL;DR: In this paper, the swelling degree of polymers with a great variety of structures, taken as solute-models, were measured and correlated with the polarity of ca. 30 solvent systems.
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Book
Principles of polymerization
TL;DR: In this paper, the authors present an overview of the properties of polymers and their applications in the literature, including the following: 1.1 Types of Polymers and Polymerization. 2.3 Linear, Branched, and Crosslinked Polymers.
Journal ArticleDOI
Theory of Molecular Size Distribution and Gel Formation in Branched Polymers II. General Cross Linking
TL;DR: In this paper, a statistical calculation of the gel point and of the molecular size distribution for cross-linked high polymers of arbitrary initial size distribution is made for crosslink polymers, which depends only on the weight-average polymerization degree of the initial polymer and the degree of cross linking.
Journal ArticleDOI
Effect of the degree of crosslinking on penetrant transport in polystyrene
TL;DR: In this paper, the effect of the degree of crosslinking of glassy polymers on the transport mechanism of penetrants was investigated using a series of divinyl benzene (DVB)-crosslinked polystyrenes of nominal crosslink ratio X from 0001 38 to 0060 mol DVB/mol styrene.