Journal ArticleDOI
Fingerprints of the carbon-nitrogen bond formation between ethylenediamine and an aldose on cobalt(III) complexes. Isotopic multiplets in the carbon-13 NMR spectra of cobalt(III) complexes with partially deuteriated coordinated amino groups
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This article is published in Journal of the American Chemical Society.The article was published on 1988-03-01. It has received 12 citations till now. The article focuses on the topics: Carbon-13 NMR & Cobalt.read more
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Peroxo-Bridged Dinuclear Cobalt(III) Complexes Containing N-Glycoside Ligands from Tris(2-aminoethyl)amine and d-Glucose or Maltose
Tomoaki Tanase,Tomoko Onaka,Masako Nakagoshi,Isamu Kinoshita,Kozo Shibata,Matsumi Doe,Junko Fujii,Shigenobu Yano +7 more
TL;DR: In this paper, the peroxo-bridged dinuclear cobalt(III) complexes were characterized by elemental analysis, UV−vis absorption, circular dichroism, 1H and 13C NMR spectroscopic techniques, and X-ray absorption and crystallographic analyses.
Journal ArticleDOI
Recent progress of functional glycoconjugated metal complexes
Shigenobu Yano,Yuji Mikata +1 more
TL;DR: In this article, the synthesis, characterizations and stereochemistry of the transition metal complexes containing glycosylamines derived from sugar molecules and polyamines have been investigated, and the biological activity of these metal complexes was also investigated.
Journal ArticleDOI
Peroxo-bridged dinuclear cobalt(III) complexes containing N-glycoside ligands from tris(2-aminoethyl)amine and D-glucose and their reversible dioxygen binding properties
Tomoaki Tanase,Tomoko Onaka,Masako Nakagoshi,Shigenobu Yano,Isamu Kinoshita,Kozo Shibata,Matsumi Doe,Junko Fujii +7 more
TL;DR: Peroxo-bridged dinuclear cobalt(III) complexes containing N-glycoside ligands from tris(2-aminoethyl)amine (tren) and D-glucose (D-Glc), and their reversible dioxygen binding properties were reported as discussed by the authors.
Journal ArticleDOI
Stereochemistry of sugar units in glycosylamine ligands of octahedral complexes derived from tris(trimethylenediamine)-nickel(II) and natural aldohexoses
Shigenobu Yano,Masako Kato,Hideki Shioi,Toshikazu Takahashi,Taro Tsubomura,Koshiro Toriumi,Tasuku Ito,Masanobu Hidai,Sadao Yoshikawa +8 more
TL;DR: In this article, the structures of the sugar units in the glycosylamine complexes from all natural aldohexoses can be classified into either the above two types, the only difference being the relative absolute configuration at C2 and C5.