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Open AccessJournal ArticleDOI

Flow-injection spectrophotometric determination of micro amounts of sulfate ion in surface- and sea-water samples with a barium chromate reaction column

Akio Sakuragawa, +2 more
- 10 Feb 1994 - 
- Vol. 10, Iss: 1, pp 77-81
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TLDR
In this paper, a rapid and simple flow-injection method using a reaction column packed with barium chromate powder is described for the determination of micro amounts of sulfate ion in surface and sea-water samples.
Abstract
A rapid and simple flow-injection method using a reaction column packed with barium chromate powder is described for the determination of micro amounts of sulfate ion in surface- and sea-water samples. An aqueous solution containing 4.5mM sodium acetate and 4% ethanol was used as a carrier solution at a flow rate of 0.8ml/min. The absorbance of the chromate ion (which corresponds to the sulfate ion concentration) in the carrier solution from the reaction column was measured using a photometric detector at 370nm. Interference from some cations was eliminated by the use of a cation-exchange resin column installed in front of the reaction column; interference from some anions was reduced by using the carrier solution mentioned above. The concentration range from 0.5 to 5ppm of the sulfate ion in practical water samples can be determined by the proposed method with good reproducibility.

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Citations
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Journal ArticleDOI

Determination of trace inorganic anions in seawater samples by ion chromatography using silica columns modified with cetyltrimethylammonium ion

TL;DR: Conventional silica columns dynamically modified with cetyltrimethylammonium ions were evaluated for the determination of UV-absorbing bromide, nitrate, and nitrite in seawater samples.
Journal ArticleDOI

Application of flowing-stream techniques to water analysis Part II. General quality parameters and anionic compounds: halogenated, sulphur and metalloid species.

TL;DR: relevant flow methods applied to the monitoring of anionic species as well as to the determination of general parameters for water quality evaluation are reviewed, and their background, detection technique and noteworthy analytical features are detailed.
Journal ArticleDOI

Flow injection spectrophotometry coupled with a crushed barium sulfate reactor column for the determination of sulfate ion in water samples

TL;DR: A new type of a reactor column, a crushed BaSO(4) reactor column used for the flow injection spectrophotometric determination of sulfate ion using the exchange reaction of sulfATE ion and barium-dimethylsulfonazo III is proposed.
Journal ArticleDOI

Determination of sulphate in water by flow-injection analysis with electrode-separated piezoelectric quartz crystal sensor

TL;DR: In this article, a new flow-injection analysis (FIA) system with detection by an electrode-separated piezoelectric quartz crystal (ESPQC) was developed for sulphate determination in water.
References
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Journal ArticleDOI

Flow Injection Analysis

TL;DR: In this paper, the effect of sample volume, tube length, tube diameter, peak height and sampling rate on the determination of phosphorus in acidic plant digests was investigated, and optimal conditions for the flow injection method were described.
Journal ArticleDOI

Flow Injection Analysis

TL;DR: This paper presents a meta-review of the Flow--Injection Literature and discusses theoretical Aspects of FIA Techniques, components of An FIA Apparatus, and Experimental Techniques and FIA Exercises.
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