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Free-radical cyclization of bromo acetals. Use in the construction of bicyclic acetals and lactones
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This article is published in ChemInform.The article was published on 1983-09-06. It has received 177 citations till now. The article focuses on the topics: Radical cyclization & Bicyclic molecule.read more
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Radicals: Reactive Intermediates with Translational Potential
TL;DR: This Perspective illustrates the defining characteristics of free radical chemistry, beginning with its rich and storied history, and studies from the laboratory are discussed along with recent developments emanating from others in this burgeoning area.
Journal ArticleDOI
Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems
TL;DR: In this paper, the authors studied the effect of intermolecular radical cyclizations and multicomponent radical cascades in solution, which are initiated by intermolescular radical addition to C-C triple bond in alkynes as well as to related C?N triple bonds in nitriles and isonitriles, arranged according to the atom that carries the unpaired electron in the attacking radical and cover main group IV-VI elements.
Journal ArticleDOI
Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated- or Transition Metal-Catalyzed Cascade Reactions.
Journal ArticleDOI
Free-radical carbon-carbon bond formation in organic synthesis.
TL;DR: Carboncentered radicals can form bonds with electron-rich or electron-deficient alkenes, allenes, and acetylenes, as well as construct hindered carbon-carbon bonds, which contribute to the importance of such reactions in organic synthesis.
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