Generation and reactions of the borate radical — A flash photolysis study

doi:10.1007/BF02840539

Open AccessDOI

Generation and reactions of the borate radical — A flash photolysis study

- Vol. 100, Iss: 4, pp 297-303

TLDR

The transient borate radical is produced by flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8 and the absorption spectrum of this radical shows two maxima as mentioned in this paper.

Abstract:

The borate radical is produced by the flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8. The absorption spectrum of the transient borate radical shows two maxima. The self decay of this radical is second order. Rate constants for the reactions of this radical with some organic substrates have been determined.

References

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Journal ArticleDOI

Flash photolysis of per[oxydi]sulfate ions in aqueous solutions. The sulfate and ozonide radical anions

Libera Dogliotti, +1 more

- 01 Jul 1967 -

The Journal of Physical Chemistry

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Carbonate radical in flash photolysis and pulse radiolysis of aqueous carbonate solutions

David Behar, +2 more

- 01 Jan 1970 -

The Journal of Physical Chemistry

Book

Boron, Metallo-Boron Compounds and Boranes

Roy M. Adams

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High-field boron-11 NMR of alkali borates. Aqueous polyborate equilibria

Christopher G. Salentine

- 01 Dec 1983 -

Inorganic Chemistry

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High-field 11B NMR of alkali borates. Aqueous polyborate equilibria

C. G. Salentine

- 01 Jan 1983 -

Inorganic Chemistry

TL;DR: Spectres RMN de 11 B a 127 and 160 MHz de solutions aqueuses de KB 5 O 8 •4H 2 O, K 2 B 5 OD 8 (OH)•2H 2 OD 7 •4 H 2 O and NaB 5 O 7 •5 H 2 OD as discussed by the authors.

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