Open AccessDOI
Generation and reactions of the borate radical — A flash photolysis study
S. Padmaja,V. Ramakrishnan,J. Rajaram,J. C. Kuriacose +3 more
- Vol. 100, Iss: 4, pp 297-303
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TLDR
The transient borate radical is produced by flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8 and the absorption spectrum of this radical shows two maxima as mentioned in this paper.Abstract:
The borate radical is produced by the flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8. The absorption spectrum of the transient borate radical shows two maxima. The self decay of this radical is second order. Rate constants for the reactions of this radical with some organic substrates have been determined.read more
References
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Journal ArticleDOI
Equilibrium Studies of Polyanions. 11. Polyborates in 3.0 M Na(Br), 3.0 M Li(Br), and 3.0 M K(Br), a Comparison with Data Obtained in 3.0 M Na(ClO4).
Journal ArticleDOI
Reactions of the carbonate radical with aliphatic amines
TL;DR: In this article, the concept of Hoffmann's "through bond" interaction was used to explain carbonate radicals' reactivities with aliphatic amines by hydrogen abstraction and electron transfer.
Journal ArticleDOI
Inorganic Radical-ions and Their Organic Reactions
A F Morkovnik,O. Yu. Okhlobystin +1 more
TL;DR: A systematic account of the available information about the simplest inorganic radical-ions O2, O, O3, CO2, SO4, etc., their reactions with organic substrates are considered, and their possible role in organic reactions is discussed as mentioned in this paper.
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