Journal ArticleDOI
Group transfer polymerization - polymerization of acrylic monomers
Reads0
Chats0
TLDR
Polymerisation vivante de methacrylates en presence of cetene silyl acetals comme amorceurs et fluorure, bifluorure, cyanure ou azide comme catalyseursAbstract:
Polymerisation vivante de methacrylates en presence de cetene silyl acetals comme amorceurs et fluorure, bifluorure, cyanure ou azide comme catalyseursread more
Citations
More filters
Journal ArticleDOI
Kinetics and stereoregulation in the isotactic‐specific and living polymerization of methyl methacrylate
TL;DR: In this paper, isotactic-specific living polymerization of methyl methacrylate with t-C4H9MgBr was carried out in toluene at −78°C and the kinetic orders with respect to the monomer and initiator were found to be unity.
Journal ArticleDOI
Synthesis and Photophysical Characterization of Group Transfer Polymers with Pendent Aryl Chromophores
Marye Anne Fox,Heike W. Thompson +1 more
TL;DR: In this article, Naphthalene-and pyrene-labeled polymers (poly-3−5) prepared by group transfer polymerization of methyl 2-(2-naphthyl)acrylate, methyl 2-1-pyrenyl) acrylate and ethyl 5-(2)-hexadienoate, respectively, were studied as probes for backbone conformational rigidity.
Journal ArticleDOI
Group-transfer polymerization of tert-butyl methacrylate and [3-(methacryloxy)propyl]pentamethyldisiloxane : Synthesis and characterization of homopolymers and random and block copolymers
TL;DR: In this paper, a synthetic approach for preparing block copolymers consisting of both a [3-(methacryloxy)propyl]pentamethyldisiloxane (SiMA) block and tert-butyl methacrylate (t-BMA), using group-transfer polymerization (GTP), was developed.
Journal ArticleDOI
Synthesis of AB block and A2B2 and A3B3 miktoarm star-shaped copolymers using ω-end-functionalized poly(methyl methacrylate) with a hydroxyl group prepared by organocatalyzed group transfer polymerization
TL;DR: In this paper, the effects of the employed catalysts, polymer chain length, and benzaldehyde derivatives on the ω-end functionalization efficiency (%F) were investigated in detail, and the electrophilic termination of the living PMMA end with benzaldehyde as the terminator produced a structurally defect-free ω end-functionalized PMMA with a hydroxyl group (PMMA-OH).