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Group transfer polymerization - polymerization of acrylic monomers
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Polymerisation vivante de methacrylates en presence of cetene silyl acetals comme amorceurs et fluorure, bifluorure, cyanure ou azide comme catalyseursAbstract:
Polymerisation vivante de methacrylates en presence de cetene silyl acetals comme amorceurs et fluorure, bifluorure, cyanure ou azide comme catalyseursread more
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Depletion flocculation in dispersions of sterically-stabilised silica particles 3. The effect of grafted chain coverage
TL;DR: In this article, the effect of coverage of grafted polymer chains on the stability of dispersions of soft sphere particles to depletion flocculation in the presence of free polymer was investigated.
Journal ArticleDOI
High-Speed Living Polymerization of Polar Vinyl Monomers by Self-Healing Silylium Catalysts
TL;DR: Fundamental steps of activation, initiation, propagation, and catalyst "self-repair" involved in this living polymerization system have been elucidated, chiefly featuring a propagation "catalysis" cycle consisting of a rate-limiting C--C bond formation step and fast release of the silylium catalyst to the incoming monomer.
Journal ArticleDOI
Stimuli‐Responsive A‐b‐(B‐co‐C) Diblock Terpolymers Bearing Polyampholyte Sequences
TL;DR: In this article, two types of block tepolymers are explored in aqueous media: the amphiphilic poly{[(diethylamino)ethyl methacrylate]-co-(methacrylic acid)}-block-poly(methyl methacelate) and the double hydrophilic poly[oligo(ethylene glycol) methacellate]-Modk-poly{[diethlamino]ethyl methacel]-co(methACrylic acid)}.
Journal ArticleDOI
Radical-initiated polymerization of β-methyl-α-methylene-γ-butyrolactone
Charles U. Pittman,Hookun Lee +1 more
TL;DR: In this paper, β-Methyl-α-methylene-γ-butyrolactone (MMBL) was synthesized and then was polymerized in an N,N-dimethylformamide (DMF) solution with 2,2-azobisisobutyronitrile (AIBN) initiation.