Journal ArticleDOI
Halogen oxidation of some group VI metal carbonyl derivatives
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TLDR
In this article, Halogen oxidation of several amine chromium and amine molybdenum carbonyls has been studied and the complexes have been identified by microanalysis, infrared spectra and conductivity measurements.About:
This article is published in Inorganica Chimica Acta.The article was published on 1976-01-01. It has received 21 citations till now. The article focuses on the topics: Amine gas treating & Metal carbonyl.read more
Citations
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Journal ArticleDOI
The synthesis and spectral properties of some highly reactive new seven-coordinate molybdenum(II) and tungsten(II) bisacetonitrile dihalogenotricarbonyl complexes
TL;DR: In this article, the seven-coordinate complexes [M(CO) 3 (NCMe) 3 ] (M = Mo and W) react with X 2 (X = Br and I) in NCMe to afford high yields of the new seven coordinate complexes.
Book ChapterDOI
The Organometallic Chemistry of Halocarbonyl Complexes of Molybdenum(II) and Tungsten(II)
Journal ArticleDOI
Oxidation of [Mo(CO)3(NCMe)3] with SnCl4 to give the seven-coordinate compound [MoCl(SnCl3)(CO)3(NCMe)2]. Reactions of [MoCl(SnCl3)(CO)3(NCMe)2] with phosphine donor ligands
Paul K. Baker,Adrian Bury +1 more
TL;DR: The trisacetonitrile complex [MoCl(CO) 3 (NCMe) 3 ] reacts in situ with an equimolar quantity of SnCl 4 to give a quantitative yield of the new seven-coordinate complex as mentioned in this paper.
Journal ArticleDOI
Transition metal derivatives of the tetracyanoquinodimethandiide ion, TCNQ2−
TL;DR: In this article, a simple organometallic compounds with tetracyanoquinodimethan (TCNQ) in acetonitrile gave metal derivatives of TCNQ 2− which were characterized by infrared and X-ray photoelectron spectroscopy and magnetic susceptibility.
Journal ArticleDOI
Homoleptic alkylisocyanide complexes of molybdenum(O) and tungsten(O), useful precursors for the synthesis of low-valent dialkylaminocarbyne complexes
TL;DR: A large scale, high yield synthesis of the homoleptic alkylisocyanide complexes M(RNC) 6 (R = Et, t Bu) and carbonyl-free diethylaminocarbyne complexes (EtNC)P 5 MCNEt 2 ]BF 4 starting from M(CO) 6(M = Mo, W) is reported.
References
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Journal ArticleDOI
Reactions of halocarbonyls of Group VIb elements. II. Complexes of molybdenum and tungsten containing group Va donors or phenyl isocyanide
Journal ArticleDOI
Photochemische Darstellung von Amin-Derivaten von Metallhexacarbonylen
TL;DR: In this paper, die Verbindungen Cr(CO)5Pip, Cr( CO)4Pip2, Mo(CO 5Pip), Mo( CO 4Pip 2, Mo (CO) 5Pipe, Mo 4Pipe 3, Mo 5Pine, Mo 6Pipe 4, Mo 7Pipe 2, W(CO 4Pine), W( CO 5N(C2H5)3), W (CO 5N)3).
Journal ArticleDOI
The Reactions of Group VI Metal Carbonyls with Pyrrolidine, Piperazine, and Morpholine
G. W. A. Fowles,D. K. Jenkins +1 more
Journal ArticleDOI
1-(Diphenylphosphino)-2-(diphenylarsino)ethane derivatives of group VI metal carbonyls
TL;DR: A tetrasubstituted molybdenum derivative [Mo(CO) 2 (dpda) 2 ] was obtained in very poor yield under more forcing conditions as discussed by the authors.