Journal ArticleDOI
Homogeneous catalysis: VIII. Carbene-transition-metal complexes as hydrosilylation catalysts
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In this paper, the addition of triethylsilane to phenylacetylene or diphenyl-acetylene, catalysed by cis-[RhCl(COD)LMe] or trans-[Rhodium(PPh3)2LMe], proceeds stereoselectively via trans-addition.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1984-03-20. It has received 134 citations till now. The article focuses on the topics: Hydrosilylation & Ultraviolet light.read more
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Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds.
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N-Heterocyclic Carbene Complexes in C–H Activation Reactions
TL;DR: Through discussing the role of NHC ligands in promoting challenging C-H activation methods, the reader is provided with an overview of this important area and its crucial role in forging carbon-carbon and carbon-heteroatom bonds by directly engaging ubiquitous C- H bonds.
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Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions
TL;DR: In this paper, the authors focus on the latest advances in homogeneous catalysis with donor-functionalised (donor = C, N, O, S or P) N-heterocyclic carbene complexes.
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N‐Heterocyclische Carbene
TL;DR: In this paper, a gegenwartige Wissensstand auf dem Gebiet der Synthese-and Strukturchemie, der Bindungstheorie, Koordinationschemie und Katalyse zusammengefast is discussed.
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Redox processes involving hydrocarbylmetal (N-heterocyclic carbene) complexes and associated imidazolium salts: ramifications for catalysis
TL;DR: In this paper, the authors review the redox processes undergone by the NHC/imidazolium salt couple in conjunction with Group 10 metals, and show that the reduction of hydrocarbyl-M-carbene complexes yields 2-substituted imidazolate salt and M(0) with factors influencing the reaction reviewed in some detail.
References
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Mechanistic features of catalytic carbon monoxide hydrogenation reactions
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Transition-Metal-Catalyzed Reactions of Diazo Compounds. 1. Cyclopropanation of Double Bonds
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Rhodium carbene complexes as hydrosilylation catalysts
J.E. Hill,Terence A. Nile +1 more
TL;DR: The catalytic activity of various rhodium carbene complexes has been investigated in this paper, showing that they are active for the hydrosilylation of a wide variety of unsaturated organic molecules such as olefins, acetylenes and dienes.
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