Journal ArticleDOI
Initial state and transition state solvation in inorganic reactions
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In this paper, the authors present an analysis of single ion properties and transition state models for a class of reactions involving neutral reactants, including substitution reactions, redox reactions, metal ion catalysed reactions, and two stage reactions.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1980-02-01. It has received 68 citations till now.read more
Citations
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Solvatochromism and solvation of ternary iron-diimine-cyanide complexes
TL;DR: In this paper, transfer chemical potentials have been derived from appropriate solubility measurements for several iron(II)-and iron(III)-diimine-cyanide complexes into aqueous methanol.
Journal ArticleDOI
Solvation of transition metal complexes: thermochemical approaches
TL;DR: In particular, informed use of solvation characteristics should help in optimising conditions for organometallic reactions and in homogeneous catalysis as discussed by the authors, and the importance of such knowledge in understanding their chemistry, particularly their reactivity.
Journal ArticleDOI
Pyrazolylimine iron and cobalt, and pyrazolylamine nickel complexes: Synthesis and evaluation of nickel complexes as ethylene oligomerization catalysts
TL;DR: A series of tridentate and bidentate iron, cobalt and nickel complexes were prepared from {2,4-di- tert -butyl-6-[(2-(3,5-RR-pyrazol-1-yl-ethylimino)methyl]-phenol}, R = H (L1 ), Me (L2 ), Ph (L3 ), and (4-(4- tert]-benzylidene)-imine) (L5 ).
Journal ArticleDOI
Solvation and reactivity of the low-spin trisdiimine iron(II) complex of the schiff base ligand derived from 2-benzoylpyridine and 3,4-dimethylaniline, [Fe(Me2bsb)3]2+
TL;DR: In this paper, the reactivity and solvation of the iron tris complex made from the bidentate ligand obtained by condensing phenyl 2-pyridyl ketone and 3,4-dimethylaniline have been examined in aqueous solution and in aaqueous solvent mixtures.
Journal ArticleDOI
Isomeric forms of tris-Schiff base complexes of iron(II): structure of the complex derived from 2-acetyl pyridine and methylamine
Michael J. Blandamer,John Burgess,Diane L. Elvidge,Pilar Guardado,Andrew W. Hakin,Lesley J. S. Prouse,Stojan Radulovic,David R. Russell +7 more
TL;DR: The structure of the tetrahydrate of the tris-ligand FeII complex of the Schiff base derived from 2-acetyl pyridine and methylamine has been established by x-ray diffraction methods as mentioned in this paper.
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Protic-dipolar aprotic solvent effects on rates of bimolecular reactions
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