Journal ArticleDOI
Intramolecular acyl radical-alkene addition reactions: macrocyclization reactions
Dale L. Boger,Robert J. Mathvink +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1990-05-01. It has received 61 citations till now. The article focuses on the topics: Organic reaction & Addition reaction.read more
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Journal ArticleDOI
Chemistry of Acyl Radicals
Journal ArticleDOI
Tandem Radical Reactions of Carbon Monoxide, Isonitriles, and Other Reagent Equivalents of the Geminal Radical Acceptor/Radical Precursor Synthon.
Journal ArticleDOI
Advances in radical conjugate additions
TL;DR: The field of radical conjugate additions, including both intramolecular and intermolecular examples, is reviewed in this paper, where the authors highlight the applications in total synthesis.
Journal ArticleDOI
Asymmetric Total Synthesis of ent-(−)-Roseophilin: Assignment of Absolute Configuration
Dale L. Boger,Jiyong Hong +1 more
TL;DR: Surprisingly, ent-(-)-1 was found to be 2-10-fold more potent than natural (+)-1 in cytotoxic assays, providing an unusually rewarding culmination to synthetic efforts that provided the unnatural enantiomer.
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Acyl radicals: intermolecular and intramolecular alkene addition reactions
Dale L. Boger,Robert J. Mathvink +1 more