Journal ArticleDOI
Chemistry of Acyl Radicals
Reads0
Chats0
About:
This article is published in Chemical Reviews.The article was published on 1999-06-24. It has received 693 citations till now. The article focuses on the topics: Acylation.read more
Citations
More filters
Journal ArticleDOI
Photochemical Reactions as Key Steps in Organic Synthesis
TL;DR: Photochemical Electron-Transfer Reactions with a Catalytic Sensitizer 1068 6.1.1 Photochemical Extrusion of Small Molecules 1067 6.2.2 Photochemical Rearrangings 1061 4.4.3.
Journal ArticleDOI
Recent Advances in Radical C-H Activation/Radical Cross-Coupling.
TL;DR: This Review provides a brief and concise overview of the current status and latest methodologies using radicals or radical cations as key intermediates produced via radical C-H activation, which includes radical addition, radical cascade cyclization, radical/radical cross-coupling, coupling of radicals with M-R groups, and coupling ofradical cations with nucleophiles (Nu).
Journal ArticleDOI
Thiyl Radicals in Organic Synthesis
TL;DR: The thiol−olefin cooxidation process was applied to the total synthesis of antimalarial agent yingzhaosu A and was extended to include the more challenging 1,5-dienes, from which six-membered ring endoperoxides can be obtained.
Journal ArticleDOI
Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.
TL;DR: This analysis comprehensively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emphasis on the nature of stereochemistry generation.
Journal ArticleDOI
Metal-Catalyzed Decarboxylative C–H Functionalization
TL;DR: An overview of the utility of decarboxylative C-H bond functionalization in the synthesis of various organic compounds, such as styrenes, chalcones, biaryls, and heterocycles, is offered, covering most of the recent advances.
References
More filters
Journal ArticleDOI
Hydrocarbon Bond Dissociation Energies
TL;DR: The best available values for homolytic bond dissociation energies (BDEs) of various classes of neutral compounds are considered in a review as mentioned in this paper, focusing on prototypical radicals whose heats of formation, formerly thought to be well in hand, have recently been called into serious question.
Journal ArticleDOI
A new method for the deoxygenation of secondary alcohols
TL;DR: In this paper, a general synthesis of O-cycloalkyl thioesters has been developed which gives access to O-cycle-alkyl seleno-formates and selenobenzoates.
Journal ArticleDOI