Journal ArticleDOI
Intramolecular rearrangement in (.eta.-diene)tricarbonyliron and -ruthenium compounds. A carbon-13 nuclear magnetic resonance study
Leonard Kruczynski,Josef Takats +1 more
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This article is published in Inorganic Chemistry.The article was published on 1976-12-01. It has received 77 citations till now. The article focuses on the topics: Diene & Intramolecular force.read more
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Journal ArticleDOI
Carbon monoxide as an intrinsic ligand to iron in the active site of the iron-sulfur-cluster-free hydrogenase H2-forming methylenetetrahydromethanopterin dehydrogenase as revealed by infrared spectroscopy.
Erica J. Lyon,Seigo Shima,Reinhard Boecher,Rudolf K. Thauer,Friedrich-Wilhelm Grevels,Eckhard Bill,Winfried Roseboom,Simon P J Albracht +7 more
TL;DR: It is reported here that Hmd contains intrinsic CO bound to the Fe, and the effect of extrinsic (12)CO, (13) CO, ( 12)CN(-), and ( 13)CN(-) on the IR spectrum of Hmd.
Book ChapterDOI
The Remarkable Features of (η4-Conjugated Diene)zirconocene and -hafnocene Complexes
TL;DR: In this article, the remarkable features of conjugated diene transition-metal complexes are discussed, including their properties as starting materials or reactive intermediates in many catalytic processes.
Journal ArticleDOI
Comprehensive Study of the Thermochemistry of First-Row Transition Metal Compounds by Spin Component Scaled MP2 and MP3 Methods
TL;DR: In this paper, the enthalpies of the dissociation reactions of the carbonyl ligand in Cr(CO)n [n = 6 (1a), 5 (1b), 4 (1c)], Fe(CO), Ni, and Co2(C6Me6) were calculated at the DFT/BP86, MP2, MP3, SCS-MP2, and SCSMP3 levels and compared with corresponding experimental data.
Journal ArticleDOI
Sterically hindered organometallics: multi-n-rotor (n=5, 6 and 7) molecular propellers and the search for correlated rotations
TL;DR: In this article, the rotational barriers of sterically encumbered complexes of the type (CnRn)MLx, where R=alkyl or aryl, n=5, 6 or 7, and MLx is an organometallic fragment, have been studied.
Book ChapterDOI
The Application of 13C-NMR Spectroscopy to Organo-Transition Metal Complexes
P.W. Jolly,R. Mynott +1 more
TL;DR: In this paper, the application of 13C-nuclear magnetic resonance (NMR) spectroscopy to organo-transition metal complexes was discussed, and the advantages and disadvantages associated with 13C NMR at high magnetic fields were discussed.