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Journal ArticleDOI

Introductory Lecture: Inertia, coarsening and fluid motion in binary mixtures

Michael E. Cates, +3 more
- 01 Jan 1999 - 
- Vol. 112, pp 1-11
TLDR
In this paper, a scaling theory is proposed to predict the dependence of a steady state domain size on shear rate, but assumes low Reynolds number (inertia is neglected).
Abstract
Symmetric binary fluids, quenched into a regime of immiscibility, undergo phase separation by spinodal decomposition. In the late stages, the fluids are separated by sharply defined, but curved, interfaces: the resulting Laplace pressure drives fluid flow. Scaling ideas (of Siggia and of Furukawa) predict that, ultimately, this flow should become turbulent as inertial effects dominate over viscous ones. The physics here is complex: mesoscale simulation methods (such as lattice Boltzmann and dissipative particle dynamics) can play an essential role in its elucidation, as we describe. Likewise, it is a matter of experience that immiscible fluids will mix, on some lengthscale at least, if stirred vigorously enough. A scaling theory (of Doi and Ohta) predicts the dependence of a steady state domain size on shear rate, but assumes low Reynolds number (inertia is neglected). Our preliminary simulation results (three-dimensional, so far only on small systems) show little sign of the kind of steady state envisaged by Doi and Ohta; they raise instead the possibility of an oriented domain texture which can continue to coarsen until either inertial effects, or (in our simulations) finite size effects, come into play.

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Citations
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The nonlinear nature of friction

TL;DR: Recent experiments coupled to theoretical modelling have made great advances in unifying apparently diverse phenomena and revealed many subtle and often non-intuitive aspects of matter in motion, which stem from the nonlinear nature of the problem.
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LUDWIG: A parallel Lattice-Boltzmann code for complex fluids

TL;DR: Ludwig as discussed by the authors is a versatile code for the simulation of Lattice Boltzmann (LB) models in 3D on cubic lattices, which is not a single code, but a set of codes that share certain common routines, such as I/O and communications.
Journal ArticleDOI

Phase-separating binary fluids under oscillatory shear.

TL;DR: This work applies the lattice Boltzmann methods to study the segregation of binary fluid mixtures under oscillatory shear flow in two dimensions and finds that at high frequencies the evolution is almost isotropic with growth exponents 2/3 and 1/3 in the inertial and diffusive regimes, respectively.
Journal ArticleDOI

Mesoscopic Simulation of Drops in Gravitational and Shear Fields

TL;DR: In this article, a pendant drop and a drop in simple she... is used to validate Dissipative Particle Dynamics (DPD) for the mesoscopic modeling of multiphase fluid−fluid systems in external fields.
Posted Content

Computer Simulations of Friction, Lubrication and Wear

TL;DR: An overview of computer simulations of tribology is presented in this paper, with a brief overview of simulation techniques and the special requirements for simulation of tribological processes, and a simple one-dimensional models of friction between crystalline surfaces are introduced to illustrate general features of friction, such as the importance of metastability and the effect of commensurability.
References
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Book

The Structure and Rheology of Complex Fluids

TL;DR: In this article, the authors present a comprehensive overview of the properties and properties of complex fluids and their properties in terms of physics, chemistry, physics theory, and physics of complex fluid properties.
Journal ArticleDOI

Dissipative particle dynamics : bridging the gap between atomistic and mesoscopic simulation

TL;DR: In this article, a review of dissipative particle dynamics (DPD) as a mesoscopic simulation method is presented, and a link between these parameters and χ-parameters in Flory-Huggins-type models is made.
Journal ArticleDOI

Lattice Boltzmann simulations of liquid-gas and binary fluid systems

TL;DR: The details of a lattice Boltzmann approach to phase separation in nonideal one- and two-component fluids are presented and the kinetics of the approach to equilibrium lie within the expected universality classes.
Journal ArticleDOI

Late stages of spinodal decomposition in binary mixtures

TL;DR: In this paper, the influence of hydrodynamic interactions on the coarsening rate of a cloud of droplets combining through diffusive coalescence is examined in detail, and the competing LifshitzSlyozov or evaporation-condensation mechanism is dominant.
Journal ArticleDOI

Dynamics and rheology of complex interfaces. I

TL;DR: In this article, a semiphenomenological kinetic equation is proposed which describes the time evolution of droplet size and orientation, and also the macroscopic stress in a flow field.