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Journal ArticleDOI

Iron-molybdenum-sulphur and iron-tungsten-sulphur complexes of diimines

Vasanthi Lakshmanan, +2 more
- 01 Jan 1993 - 
- Vol. 12, Iss: 12, pp 1487-1490
TLDR
In this article, the linearity of the χ −1` M vs T plot and Mossbauer spectral parameters (δ: 0.28 mm s −1 ; E Q : 0.37 mm −1 ) of [Fe(bipy) 2 MoS 4 ] suggested that iron(II) assumes a distorted octahedral geometry with an intermediate spin state.
About: 
This article is published in Polyhedron.The article was published on 1993-01-01. It has received 1 citations till now. The article focuses on the topics: Octahedral molecular geometry & Denticity.

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Book ChapterDOI

Charge Transfer Phenomena in Transition Metal Sulphur Chemistry

Wolfgang Kaim, +5 more
- 01 Jan 1998 - 
TL;DR: Sulphide ions are well suited to connect metal centers of very different oxidation states and characteristics as discussed by the authors, which is an ability that is relevant for both biochemical and industrial catalysis.
References
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Journal ArticleDOI

Syntheses and characterization of ammonium and tetraalkylammonium thiomolybdates and thiotungstates

John W. McDonald, +3 more
- 01 Jan 1983 - 
TL;DR: In this paper, improved methods for the preparation of [NH4]2[MO2S2] and [NH 4 ]2[MS4] are summarized and new syntheses of [ NH 4]2 [MOS3] are reported (M = Mo, W).
Journal ArticleDOI

Charge-transfer and intraligand electronic spectra of bipyridyl complexes of iron, ruthenium, and osmium. I. Bivalent complexes

GM Bryant, +2 more
- 01 Jan 1971 - 
TL;DR: In this paper, a series of spin-paired bivalent bipyridyl complexes of iron, ruthenium, and osmium, of the type [M(bipy)3]2+, [mipy]2X2Y2]n+ have been prepared.
Journal ArticleDOI

Fe-M-S complexes derived from MS42- anions (M = molybdenum, tungsten) and their possible relevance as analogs for structural features in the molybdenum site of nitrogenase

Dimitri Coucouvanis
- 01 Jul 1981 - 
Journal ArticleDOI

Novel series of six-coordinated iron(II) diimine complexes with half-quenched spin

E. Koenig, +1 more
- 01 Sep 1968 - 
Journal ArticleDOI

The Infrared Spectra of Rare Earth Metal Chloride Complexes of 2,2'-Bipyridyl and 1,10-Phenanthroline from 650 to 70 Cm-11

John R. Ferraro, +2 more
- 01 Mar 1966 - 
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