Journal ArticleDOI
Is there a liquid-liquid phase transition in supercooled water?
TLDR
In this paper, a two-level model of liquid supercooled water is proposed to show evidence of a liquid-liquid phase transition in liquid super-cooled liquid. But this model is based on the two known forms of amorphous ice: the low-density amorphus ice (LDA) and the high-density Amorphous Ice (HDA).Abstract:
Previous studies of the structure of liquid water under pressure performed by neutron diffraction allowed us to establish two structural limits in liquid water. These two limits are closely connected to the two known forms of amorphous ice: the low-density amorphous ice (LDA) and the high-density amorphous ice (HDA). In the present paper, we propose some interpretation of our data in terms of a "two-level"–type model of water. This leads to show some evidence of a liquid-liquid phase transition in liquid supercooled water. The result looks in agreement with recent computer simulations that incorporate the two forms of amorphous ice.read more
Citations
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Journal ArticleDOI
The relationship between liquid, supercooled and glassy water
Osamu Mishima,H. Eugene Stanley +1 more
TL;DR: This article showed that water can exist in two distinct "glassy" forms, low and high density amorphous ice, which may provide the key to understanding some of the puzzling characteristics of cold and supercooled water.
Journal ArticleDOI
Relationship between structural order and the anomalies of liquid water
TL;DR: This work identifies a structurally anomalous region that encloses the entire range of temperatures and densities for which the anomalous diffusivity and thermal expansion coefficient of water are observed, and enables us to quantify the degree of structural order needed for these anomalies to occur.
Journal ArticleDOI
Supercooled and glassy water
TL;DR: The authors summarizes the known experimental facts and reviews critically theoretical and computational work aimed at interpreting the observations and providing a unified viewpoint on cold, non-crystalline, metastable states of water.
Journal ArticleDOI
Water: A Tale of Two Liquids
Paola Gallo,Katrin Amann-Winkel,Charles Angell,Mikhail A. Anisimov,Frédéric Caupin,Charusita Chakravarty,Erik Lascaris,Thomas Loerting,Athanassios Z. Panagiotopoulos,John Russo,Jonas A. Sellberg,Harry Eugene Stanley,Hajime Tanaka,Carlos Vega,Limei Xu,Lars G. M. Pettersson +15 more
TL;DR: The behavior of water in the regime from ambient conditions to the deeply supercooled region is described and some of the possible experimental lines of research that are essential to complete a global picture that still needs to be completed.
Journal ArticleDOI
Supercooled and glassy water
TL;DR: In this article, a coherent interpretation of water's properties is beginning to emerge from recent experimental and theoretical investigations, and a cold, non-crystalline states play an important role in understanding the physics of liquid water.
References
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Journal ArticleDOI
Liquid-Liquid Phase Transition: Evidence from Simulations
TL;DR: In this article, a first-order liquid-liquid phase transition is identified by evaluating the pressure-density isotherms above and below a critical temperature, by finding the presence of two coexisting phases differing by 15% in density.
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