Journal ArticleDOI
Isolation and characterization of 1,2-dilithio[tetrakis(trimethylsilyl)]ethane. The first crystal structure of nonconjugated 1,2-dilithioethane
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This article is published in Journal of the American Chemical Society.The article was published on 1989-05-01. It has received 48 citations till now. The article focuses on the topics: Trimethylsilyl.read more
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Verzerrte Moleküle : Störungsdesign, Synthesen und Strukturen
Hans Bock,Klaus Ruppert,Christian Näther,Zdenek Havlas,Hans-Friedrich Herrmann,Claudia Arad,Ilka Göbel,Andreas John,Jochen Meuret,Sabine Nick,Andreas Rauschenbach,Wolfgang Seitz,Thorsten Vaupel,Bahman Solouki +13 more
TL;DR: In this paper, the authors describe a "struktur eines Molekuls kann sich with seiner Energie and damit seiner Elektronenverteilung innerhalb der Zeitskala dynamischer Relaxation" betrachtlich andern, deren Synthese, Handhabung, and Strukturbestimmung -unter extremen und vor allem weitgehend aprotischen Bedingungen fuhrt.
Journal ArticleDOI
Isolable Anion Radical of Blue Disilene (tBu2MeSi)2SiSi(SiMetBu2)2 Formed upon One-Electron Reduction: Synthesis and Characterization
TL;DR: An electron spin resonance (ESR) study of the hyperfine coupling constants of the (29)Si nuclei indicates that rapid spin exchange occurs between these central Si atoms on the ESR time scale.
Journal ArticleDOI
Synthesis and Characterization of a Cyclobutadiene Dianion Dilithium Salt: Evidence for Aromaticity
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