Journal ArticleDOI
Kinetics of methanol homologation
TLDR
In this article, the kinetics of the methanol homologation reaction promoted by cobalt phosphine/iodine catalysts were studied by operating under batch conditions, and four main reactions were identified as the most reliable on the basis of kinetic data and mechanistic considerations.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1990-01-15. It has received 7 citations till now. The article focuses on the topics: Homologation reaction & Chemical reaction.read more
Citations
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Journal ArticleDOI
Potential Routes for Thermochemical Biorefineries
TL;DR: In this paper, a critical review focuses on potential routes for the multi-production of chemicals and fuels in the framework of thermochemical biorefineries, in particular for the selection of the mix of co-products, as well as for the sustainability.
Journal ArticleDOI
Transition metals in organic synthesis: Hydroformylation, reduction, and oxidation: Annual survey covering the year 1990☆
László Markó,Ferenc Ungváry +1 more
Journal ArticleDOI
Influence of the vapor–liquid equilibria (VLE) on the kinetics in gas–liquid and gas–liquid–solid systems
TL;DR: In this article, the mass balance equations for describing the partition of the components affecting their concentration in liquid phase also considering, when necessary, the non-ideal behaviour of the involved phases.
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An application of the UNIFAC-RKS method to a reactive system
TL;DR: Santacesaria and Triunfo as discussed by the authors extended the UNIFAC-VIRIAL method for describing vapour-liquid equilibria at high pressure and temperature for ternary mixtures and to a multicomponent reactive system.
References
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Journal ArticleDOI
Thermodynamic functions of the solubilities of gases in liquids at 25.deg.
Emmerich Wilhelm,Rubin Battino +1 more
Journal ArticleDOI
Synthetic and Mechanistic Aspects of Inorganic Insertion Reactions. Insertion of Carbon Monoxide
TL;DR: In this article, the synthetic potential and mechanistic aspects of inorganic insertion reactions of carbon monoxide, especially into metal-carbon σ-bonds, are considered, and it is shown that the CO insertion proceeds by alkyl migration; this is likely to be a general feature of all such reactions.
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Synthesis and characterization of [RuCo3(CO)12]- clusters. Effective catalyst precursors for the homologation of methanol
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Methanol carbonylation as an alternate route to chemicals
TL;DR: Ruthenium complexes have been employed as cocatalysts, and phosphine ligands have been used as modifiers of cobalt carbonyl, generally effecting greater catalyst stability and ethanol selectivity.