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Journal ArticleDOI

Kinetics of substitution at bis-cyclopentadienylvanadium dichloride

Saad M. Alshehri, +3 more
- 01 Jan 1997 - 
- Vol. 29, Iss: 11, pp 835-838
TLDR
In this paper, rate constants for substitution at vanadium(IV) in bis-cyclopentadienylvanadium dichloride by a range of anionic and uncharged nucleophiles in acetonitrile solution were derived.
Abstract: 
Rate constants are reported for substitution at vanadium(IV) in bis-cyclopentadienylvanadium dichloride by a range of anionic and uncharged nucleophiles in acetonitrile solution. Rate constants have been determined for replacement of the first and of the second chloride. The reactivity of V(cp)2Cl2 is compared with that of Ti(cp)2Cl2. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 835–838, 1997

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Citations
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Book ChapterDOI

Hydroxypyranones, hydroxypyridinones, and their complexes

John Burgess, +1 more
- 31 Dec 2008 - 
Book ChapterDOI

The interpretation and mechanistic significance of activation volumes for organometallic reactions

Rudi van Eldik, +1 more
- 01 Jan 2006 - 
TL;DR: The breadth of techniques and variety of reaction-monitoring methods described in this chapter has added broader scope, interest, and depth to this account.
Journal ArticleDOI

Chapter 28. Mechanisms of reactions in solution

N. Winterton
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Chapter 12. Vanadiumm, niobium and tantalum

J. Malito
References
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Journal ArticleDOI

Bis-cyclopentadienyl Compounds of Ti, Zr, V, Nb and Ta

G. Wilkinson, +1 more
- 01 Sep 1954 - 
Journal ArticleDOI

Hydrolysis chemistry of the metallocene dichlorides M(η5-C5H5)2Cl2, M=Ti, V, Zr. Aqueous kinetics, equilibria, and mechanistic implications for a new class of antitumor agents

Jeffrey H. Toney, +1 more
- 01 Jan 1985 - 
Journal ArticleDOI

Titanocene dichloride--the first metallocene with cancerostatic activity.

Hartmut Köpf, +1 more
- 01 Jun 1979 - 
Journal ArticleDOI

Complexes of Aluminum Chloride and Methylaluminum Dichloride with Bis-(cyclopentadienyl)-titanium Dichloride as Catalysts for the Polymerization of Ethylene1

Wendell P. Long
- 01 Oct 1959 - 
Journal ArticleDOI

Pseudohalide and chelate complexes of bis(cyclopentadienyl)vanadium(IV)

Gerald Doyle, +1 more
- 01 Dec 1968 - 
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