Journal ArticleDOI
Macroelectrode voltammetry in toluene using a phosphonium-phosphate ionic liquid as the supporting electrolyte
Noel W. Duffy,Alan M. Bond +1 more
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In this paper, the ability of the ionic liquid trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (aph4.cph12) to act as an ionic conductor in toluene has been investigated at platinum and glassy carbon macrodisc electrodes.About:
This article is published in Electrochemistry Communications.The article was published on 2006-05-01. It has received 50 citations till now. The article focuses on the topics: Ionic liquid & Supporting electrolyte.read more
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Physical and electrochemical properties of low-viscosity phosphonium ionic liquids as potential electrolytes
TL;DR: A new group of room temperature ionic liquids based on triethylalkylphosphonium cations together with a bis(trifluoromethylsulfonyl)imide anion as a novel electrolyte is presented in this paper.
Journal ArticleDOI
Ionic Liquids as Electrolytes for the Development of a Robust Amperometric Oxygen Sensor
TL;DR: A simple Clark-type online electrochemical cell design, consisting of a platinum gauze working electrode and incorporating ionic liquids (IL) as electrolytes, has been successfully applied for the amperometric sensing of oxygen, with intriguing utility in nonstandard conditions and long-term online applications.
Journal ArticleDOI
Physicochemical properties of phosphonium-based and ammonium-based protic ionic liquids†
TL;DR: In this paper, the ion conduction behavior of the PILs can be adequately described by the Vogel-Fulcher-Tamman (VFT) equation, and the higher ionic conductivity of the phosphonium-based PIL is attributed to their weaker hydrogen bond and Coulombic interactions as well as higher carrier ion concentrations, indicated by infrared analysis, lattice potential energy estimation and VFT fitting results.
Journal ArticleDOI
Phosphonium-based protic ionic liquid as electrolyte for carbon-based supercapacitors
TL;DR: In this paper, a solution of a phosphonium protic ionic liquid in acetonitrile was used as an electrolyte for carbon-based supercapacitors with an operating voltage of 15 V and capacities comparable to conventional aqueous electrolytes.
Journal ArticleDOI
Development of a voltammetric electronic tongue for discrimination of edible oils
TL;DR: A novel strategy to perform cyclic voltammetric measurements with a platinum microelectrode directly in edible oil samples is presented, which allows oil discrimination according to their quality and geographical origin.
References
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Book
CRC Handbook of Chemistry and Physics
TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Book
Smithells metals reference book
TL;DR: In this paper, the authors present an X-ray analysis of metallic materials and their properties, such as elastic properties, damping capacity and shape memory alloys, as well as their properties of metal and alloys.
Journal ArticleDOI
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
TL;DR: The first systematic study of the effect of impurities and additives (e.g., water, chloride, and cosolvents) on the physical properties of room-temperature ionic liquids was performed in this article.
Journal ArticleDOI
Efficient production of C60 (buckminsterfullerene), C60H36, and the solvated buckide ion
R. E. Haufler,J. Conceicao,L. P. F. Chibante,Y. Chai,N. E. Byrne,Scott Flanagan,Michael M. Haley,Sean C. O'Brien,C. Pan +8 more
TL;DR: Buckminsterfullerene, C{sub 60}, was prepared in gram quantities by contact-arc vaporization of a graphite rod in a 100-Torr atmosphere of helium, followed by extraction of the resultant graphite soot with toluene as discussed by the authors.