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Journal ArticleDOI

Measurement of excited‐state‐absorption loss for Ce3+ in Y3Al5O12 and implications for tunable 5d→4f rare‐earth lasers

Ralph R. Jacobs, +2 more
- 01 Sep 1978 - 
- Vol. 33, Iss: 5, pp 410-412
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TLDR
In this article, optical probe measurements of excited Ce3+ ions in Y3Al5O12 show that stimulated emission in the 550-610nm region is not possible at 295 K because of excited state absorption.
Abstract
Broad bandwidth 5d→4f transitions in Ce3+ have been considered for tunable laser action. In this letter, optical probe measurements of excited Ce3+ ions in Y3Al5O12 show that stimulated emission in the 550–610‐nm region is not possible at 295 K because of excited‐state absorption. Transient measurements demonstrate that part of this loss has ≈75‐ns lifetime and is associated with absorption from the lowest 5d level; a longer‐lifetime loss is also observed. The excited‐state‐absorption loss is reduced at lower temperatures.

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Light-radiating semiconductor component with a luminescence conversion element

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Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs

TL;DR: In this paper, a blue light emitting diode (LED) pumped white LED with yellow emitting (YAG:Ce) phosphor using addition of Pr and Tb as a co-activator and host lattice element, respectively.
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An empirical relation fitting the position in energy of the lower d-band edge for Eu2+ or Ce3+ in various compounds

TL;DR: In this article, the position of the d-band edge (E) in energy for rare earth ions that fluoresce with broad emission bands is known to be sensitive to electron-electron repulsion between the active cation and its surrounding anions.
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Tunable solid-state lasers

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TL;DR: In this paper, the basic physics of tunable solid-state lasers and the characteristics of the most significant established and emerging systems are discussed, with particular emphasis on trivalent transition metals; alexandrite, other Cr-doped systems, and Ti: sapphire.
References
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Journal ArticleDOI

Investigation of Some Ce3+‐Activated Phosphors

TL;DR: In this paper, the fluorescence of a number of new Ce3+activated phosphors is described and discussed, and conditions for visible Ce3−activated phosphor emission are indicated, viz., large crystal-field splittings (Y3Al5O12−Ce) or a large Stokes shift (SrY2O4•Ce).
Journal ArticleDOI

Nonradiative decay from 5d states of rare earths in crystals

TL;DR: In this paper, nonradiative decay from 4fn−1 5d states was investigated for trivalent rare earths in Y3Al5O12, and the rates of both 5d→4f and 5d →5d transitions were determined from measurements of the lifetimes and intensities of 5d fluorescence from Ce3+ and Pr3+.
Book ChapterDOI

The influence of charge-transfer and rydberg states on the luminescence properties of lanthanides and actinides

G. Blasse
TL;DR: In this paper, the influence of charge transfer and rydberg (f n−1 d) states on the luminescence of lanthanides and actinides (more specifically hexavalent uranium) is demonstrated.
Journal ArticleDOI

VUV fluorescence of Nd3+‐, Er3+, and Tm3+‐doped trifluorides and tunable coherent sources from 1650 to 2600 Å

TL;DR: In this article, the threshold power for laser action in these crystals by optical pumping has been estimated, using a molecular H2 laser as a pumping source, a laser system which is tunable from 1650 to 2600 A could be constructed.
Journal ArticleDOI

uv fluorescence of cerium‐doped lutetium and lanthanum trifluorides, potential tunable coherent sources from 2760 to 3220 Å

TL;DR: In this paper, the authors reported the five-peak excitation spectrum expected for the 5d state of Ce3+ in a noncubic crystal field is observed, and the fluorescence quantum yields for LaF3 and LuF3 are 0.9 and 0.82, respectively.
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