Journal ArticleDOI
Metal derivatives of tetrazoles
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In this article, the synthesis, structure, properties and applications of metal derivatives of tetrazoles are generalised and described systematically, and compounds based on the anionic and neutral tetrazole forms, C- and N-mono- and C,N-disubstituted tetrazolas are considered.Abstract:
Published data on the synthesis, structure, properties and applications of metal derivatives of tetrazoles are generalised and described systematically. Compounds based on the anionic and neutral tetrazole forms, C- and N-mono- and C,N-disubstituted tetrazoles are considered.read more
Citations
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In situ hydrothermal synthesis of tetrazole coordination polymers with interesting physical properties
TL;DR: This study obtained a myriad interesting metal-organic coordination polymers that not only partially showed the role of the metal species in the synthesis of tetrazole compounds but also provided a class of complexes displaying interesting chemical and physical properties.
Journal ArticleDOI
Medicinal chemistry of tetrazoles
TL;DR: In this paper, the properties of responsible for biological activity tetrazoles are considered and examples are given of active pharmaceutical ingredients of modern drugs containing the tetrazole ring in the molecular structure.
Journal ArticleDOI
Coordination polymers and metal–organic frameworks based on poly(pyrazole)-containing ligands
TL;DR: In this article, a survey on transition metal containing coordination polymers and metal-organic frameworks (MOFs) with poly(pyrazole)-and poly (pyrazolate)-based ligands is presented, where up to three N-donor heterocyclic rings are organized on rigid or flexible cores.
Journal ArticleDOI
Synthesis of 5‐Substituted 1H‐Tetrazoles from Nitriles and Hydrazoic Acid by Using a Safe and Scalable High‐Temperature Microreactor Approach
TL;DR: The most common synthetic approach to prepare 5-substituted 1H-tetrazole derivatives involves the addition of azide salts to organic nitriles in a temperature range of typically 100–150 8C (Scheme 1).
Journal ArticleDOI
Colloidal Nanocrystal-Based Gels and Aerogels: Material Aspects and Application Perspectives
TL;DR: Gels and aerogels manufactured from a variety of metal and semiconductor nanoparticles available in colloidal solutions have recently proven to provide an opportunity to marry the nanoscale world with that of materials of macro dimensions that can be easily manipulated and processed while maintaining the nano-scale properties as mentioned in this paper.
References
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Journal ArticleDOI
Novel, Acentric Metal–Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis
TL;DR: The pyridyltetrazolate ligand formed in situ from NaN3 and 3-cyanopyridine in the presence of ZnCl2 or CdCl2 in water affords acentric (1) or chiral (2) coordination polymers, respectively as mentioned in this paper.
Journal ArticleDOI
Cooperative phenomena and light-induced bistability in iron(II) spin-crossover compounds
TL;DR: In this article, the transition from the 1A1 low-spin state at low temperatures to the 5T2 high-spin states at elevated temperatures is accompanied by a large increase in metal-ligand bond lengths.
Journal ArticleDOI
Hydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand.
Xiang Xue,Xi-Sen Wang,Li-Zhong Wang,Ren-Gen Xiong,Brendan F. Abrahams,Xiao-Zeng You,Zi-Ling Xue,Chi-Ming Che +7 more
TL;DR: The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1H-tetrazoles.
Journal ArticleDOI
[N2H5]+2[N4C−NN−CN4]2-: A New High-Nitrogen High-Energetic Material
Anton Hammerl,Thomas M. Klapötke,Heinrich Nöth,Marcus Warchhold,Gerhard Holl,Manfred Kaiser,Uldis Ticmanis +6 more
TL;DR: The reaction of [N2H5]-2[SO4]2- with barium 5,5‘-azotetrazolate gave new high energy density materials (HEDM) based on the 5, 5‘ -azotetzolate dianion as mentioned in this paper.