Journal ArticleDOI
Metallkomplexe mit Polyaminen VII: Diamine und Silber(I)
TLDR
In this paper, the equilibria in solutions containing each one of the diamines H2N(CH2)nNH2, with n = 3 (pn), n = 4 (tn) and n = 5 (cad), piperazin (pip), and triethylenediamine (enpip) in presence of an excess of silver nitrate have been investigated.Abstract:
The equilibria in solutions containing each one of the diamines H2N(CH2)nNH2, with n = 3 (“pn”), n = 4 (“tn”), n = 5 (“cad”), piperazin (“pip”) and triethylenediamine (“enpip”) in presence of an excess of silver nitrate have been investigated. Values are given for the stability constants of the complexes: Ag(pn)+, Ag(tn)+, Ag(cad)+, Ag(pip)+, Ag(enpip)+, the hydrogen complexes: Ag(Hpn)+2, Ag(Htn)+2, Ag(Hpip)+2 and the bimetallic complexes: Ag2(pn)+2, Ag2(pip)+2.read more
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Dissertation
Thermodynamics and kinetics of aqueous piperazine with potassium carbonate for carbon dioxide absorption
Journal ArticleDOI
Komplexone XXX. Diäthylentriamin-pentaessigsäure (DTPA)†
TL;DR: In this article, the stability constants of DTPA-EDTA-complexes with metal cations were determined using 7 methods, and the stability of these species with Ca, Mn, FeII, FeIII, Co, Ni, Cu, Zn, Cd, Pb, Hg, Ce have been determined.
Book ChapterDOI
The General, Selective, and Specific Formation of Complexes by Metallic Cations
TL;DR: In this article, the overwhelming majority of reactions used to detect or determine metallic ions in aqueous solution involve the replacement of water molecules in the hydration shell by other ligands.
Journal ArticleDOI
Modeling temperature dependency of amine basicity using PCM and SM8T implicit solvation models.
TL;DR: The temperature dependency of pK(a) values of amines provides a basis for selection for optimum solvents for postcombustion CO(2) capture processes.
Journal ArticleDOI
Complex formation of N-donor ligands with group 11 monovalent ions
TL;DR: In this article, the influence of different basicities and steric properties of ligands, together with the solvation of the species involved, on the stability and nature of the resulting Ag(I) complexes is discussed.