Patent
Method for manufacturing glycosamine analoga
TLDR
In this article, a method for the production of glycosamine analogues (I) from natural carbohydrates, i.e. 5- or 6-ring glycals, involves reacting the glycal with a nitroalkane to give a carbohydrate 2-C-N-analogue in which the nitrogen is in the form of a Nitro group and reducing this to (I).Abstract:
A method for the production of glycosamine analogues (I) from natural carbohydrates , i.e. 5- or 6-ring glycals, involves (a) reacting the glycal with a nitroalkane to give a carbohydrate 2-C-N-analogue in which the nitrogen is in the form of a nitro group and (b) reducing this to (I).read more
References
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Journal ArticleDOI
Synthesis of the C-5 homologue of N-acetylneuraminic acid by enzymatic chain elongation of 2-C-acetamidomethyl-2-deoxy-D-mannose
Klaus Koppert,Reinhard Brossmer +1 more
TL;DR: The first known C-5 branched homologue of hexopyranosid-2-ulose is N-acetylmannosamine as discussed by the authors, which was converted to the first known N-5 homologue by deblocking and acid hydrolysis.