Journal ArticleDOI
Model electrochemical interfaces in ultra-high vacuum : solvent-induced surface potential profiles on Pt(111) from work-function measurements and infrared Stark effects
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In this article, the influence of various solvents upon the interfacial-potential profile on Pt(111) has been investigated by means of work function changes and infrared frequency Stark shifts attending sequential-molecular dosing in ultra-high vacuum (UHV) at a suitably low temperature (ca. 100 K).About:
This article is published in Surface Science.The article was published on 1995-08-01. It has received 41 citations till now. The article focuses on the topics: Solvation & Work function.read more
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Characterization of Corrosion Interfaces by the Scanning Kelvin Probe Force Microscopy Technique
TL;DR: In this article, a variety of interfaces relevant to corrosion processes were examined by the scanning Kelvin probe force microscopy (SKPFM) technique in order to study the influences of various parameters on the measured potential.
Journal ArticleDOI
Measurement of the surface charge density of CO-saturated Pt(1 1 1) electrodes as a function of potential: the potential of zero charge of Pt(1 1 1)
TL;DR: In this paper, the potential of zero charge (pzc) of a CO-covered Pt(1.1) electrode in a 0.1-M HClO4 solution was derived from measurements of the charge flowing upon immersion, at controlled potential.
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Potentials of Zero Charge for Platinum(111)−Aqueous Interfaces: A Combined Assessment from In-Situ and Ultrahigh-Vacuum Measurements
TL;DR: In this article, the potential of zero total charge for the Pt(111)−acidic aqueous 0.1 M HClO4 interface is derived from UHV-based work function data.
Journal ArticleDOI
Dependence of the Potential of Zero Charge of Stepped Platinum (111) Electrodes on the Oriented Step-Edge Density: Electrochemical Implications and Comparison with Work Function Behavior
TL;DR: In this paper, the dependence of the potential of zero charge (pzc) for Pt(111) surfaces in acidic aqueous solution having increasing densities of ordered monoatomic steps in the (111)−(110) and (111)-−(100) zones is evaluated from CO "charge-displacement" measurements, with the objective of elucidating the influence of the electrochemical double layer on the large step-induced changes in surface potential known for the clean uncharged surfaces in ultrahigh vacuum (UHV).
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Historical development of theories of the electrochemical double layer
B. B. Damaskin,Oleg A. Petrii +1 more
TL;DR: In this paper, the role of the thermodynamic theory of electrocapillarity of perfectly polarizable electrodes in the development of interfacial electrochemistry is emphasized, and some recent experimental data are analyzed for selected models.
References
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Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
Book
Standard Potentials in Aqueous Solution
TL;DR: Standard Potentials in Aqueous solution as mentioned in this paper is a collection of thermodynamic data from the IUPAC Commissions onElectrochemistry and Electroanalytical Chemistry, and it is a valuable supplementarytext for undergraduate and graduate-level chemistry students.
Book
The Donor-Acceptor Approach to Molecular Interactions
TL;DR: In this article, an extension of the donor-acceptor concept, characterized by the comparison between equilibrium structures in different molecular environments, is presented, in which changes in the positions of the nuclei are taken into account and the question of the nature of the molecular forces is no longer important.