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Open AccessJournal ArticleDOI

Molecular weight determination for 1,2,1,2-polypropadiene

TLDR
In this article, it was shown that the molecular weight of polybromopropadiene increases with polymerization time until a steady value is reached, and that chain transfer must occur when a constant molecular weight has been reached.
About
This article is published in European Polymer Journal.The article was published on 1980-01-01 and is currently open access. It has received 1 citations till now. The article focuses on the topics: Chain transfer & Polymerization.

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Journal ArticleDOI

Gel permeation chromatography: A guide to data interpretation

TL;DR: The importance of data produced by gel permeation chromatography (GPC) in polymer engineering is emphasized in this paper, where the steps involved in deriving a differential molecular weight distribution curve (dMWD) from the chromatogram obtained by GPC are outlined.
Journal ArticleDOI

Catalytic regular polymerization of propadiene and alkylpropadienes

TL;DR: In this article, the catalytic linear polymerization of propadiene, 1,2-butadiene and 3-methyl-1, 2, 2-Butadiene was achieved with low-valent-nickel complexes as homogeneous catalysts.
Journal ArticleDOI

Block copolymers of styrene, isoprene, and ethylene oxide prepared by anionic polymerization. I. Synthesis and characterization

TL;DR: In this paper, two types of poly(ethylene oxide) (PEO) copolymers, PEO-PI, PS-PI-PEO and PS-PS, with varying PEO block length, have been prepared, using potassium naphthalene as the initiator and tetrahydrofuran as the solvent.
Journal ArticleDOI

An investigation of the catalytic systems Co(acac)2or3, C3H4, (iBu)3Al for the polymerization of propadiene

TL;DR: In this paper, it was shown that the cobalt catalyst is formed via an equilibrium with (iBu)3Al which indicates that the active catalyst complex is bimetallic.
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