Journal ArticleDOI
Multiple metal-carbon bonds. 39. Preparation of molybdenum and tungsten neopentylidyne complexes of the type M(CCMe3)(O2CR)3, their reactions with acetylenes, and the x-ray structure of the .eta.3-cyclopropenyl complex W[C3(CMe3)Et2](O2CCH3)3
Richard R. Schrock,John S. Murdzek,John H. Freudenberger,Melvyn Rowen Churchill,Josephh W. Ziller +4 more
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This article is published in Organometallics.The article was published on 1986-01-01. It has received 40 citations till now. The article focuses on the topics: Molybdenum & Tungsten.read more
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Journal ArticleDOI
Alkyne metathesis on the rise.
TL;DR: The early years of alkyne metathesis were marked by a somewhat ironic state of affairs: the proposed mechanism was swiftly validated and more than one effective catalyst became available shortly after the discovery of this transformation; surprisingly, however, the impact on synthesis remained very limited for a long period of time.
Journal ArticleDOI
High-oxidation-state molybdenum and tungsten alkylidyne complexes
Book ChapterDOI
Bulky or Supracyclopentadienyl Derivatives in Organometallic Chemistry
TL;DR: In this article, the authors focus on supracyclopentadienyl derivatives in organometallic chemistry and present a large number of them as ligands in metal complexes.
Book ChapterDOI
Recent Advances in the Chemistry of Metal-Carbon Triple Bonds
Andreas Mayr,Hans Hoffmeister +1 more
TL;DR: The first transition-metal carbyne complexes were synthesized in Fischer's laboratory by the treatment of alkoxycarbene pentacarbonyl metal complexes of chromium, molybdenum, and tungsten with boron trihalides as mentioned in this paper.
Book ChapterDOI
Transition metal complexes with terminal carbyne ligands
TL;DR: The chemistry of molecular carbyne complexes has been extensively studied in the literature as mentioned in this paper, and there is also much interest in them as models for species that are possibly present on metal surfaces in catalytic reactions.