Journal ArticleDOI
New Extensions of the Anionic Oxy-Cope/Intramolecular SN' Reaction Cascade
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TLDR
In this paper, the exo carbinol 3 and endo CARBINOL 7 can be easily transformed into the relatively complex end products 6 and 11, respectively, upon appropriate exposure to basic conditions.About:
This article is published in Synthetic Communications.The article was published on 1998-04-01. It has received 4 citations till now. The article focuses on the topics: Intramolecular force.read more
Citations
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Journal ArticleDOI
SNi′ displacements with main group organometallics
Book ChapterDOI
One or More CH, CC, and/or C C Bond(s) Formed by Rearrangement
M. Molina,José Marco-Contelles +1 more
TL;DR: This paper reviewed rearrangement reactions that form a double bond and the period covered is 1995 to 2003, with a broad scope and although major emphasis given to synthetic aspects, especially in the area of natural products synthesis, mechanistic (and computational calculations) and stereochemical features (including asymmetric catalysis) are also mentioned.
Journal ArticleDOI
New Extensions of the Anionic Oxy‐Cope/Intramolecular SN′ Reaction Cascade.
TL;DR: In this article, the exo carbinol 3 and endo CARBINOL 7 can be easily transformed into the relatively complex end products 6 and 11, respectively, upon appropriate exposure to basic conditions.
Journal ArticleDOI
An Organocatalytic Oxy-Cope/Michael Cascade Reaction.
TL;DR: In this paper , an iminium ion activation was used to catalyse the oxy-Cope rearrangement of 4-hydroxy-and 4-alkoxy-1,5-hexadiene-2-carboxaldehydes via an intramolecular Michael reaction.
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Journal ArticleDOI
Intramolecular SN' cleavage of allylic ethers by enolate anions
TL;DR: In this article, it was shown that bimolecular nucleophilic substitution of allyl alkyl ethers can be done with allyl allyl ethers, perhaps because of a predetermination that these systems would prove as inert toward displacement as dialkyl alkyls.
Journal ArticleDOI
Synthetic studies on furanoheliangolides. Stereocontrolled construction of the oxygen-bridged tricyclic framework
Dearg S. Brown,Leo A. Paquette +1 more
TL;DR: In this paper, the heavily functionalized 6,9-epoxycyclodeca[b]furan-11-ones 34 and 37 have been prepared in 13 steps from 4-methyl-2-[(phenylmethoxy)methyl]-furan.