New ligands for manganese catalysed selective oxidation of sulfides to sulfoxides with hydrogen peroxide
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TLDR
In situ prepared manganese complexes with ligands 1 -5 have been used in the catalytic oxidation of sulfides to sulfoxides using hydrogen peroxide at 0°C in acetone.About:
This article is published in Tetrahedron Letters.The article was published on 2001-06-11 and is currently open access. It has received 81 citations till now. The article focuses on the topics: Hydrogen peroxide & Sulfone.read more
Citations
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Enantioselective synthesis of sulfoxides: 2000-2009.
TL;DR: Oxidation with Chiral Oxaziridines 4309 1.2.1.
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Oxidation of sulfides to sulfoxides. Part 2: Oxidation by hydrogen peroxide
TL;DR: In this article, the authors reviewed the oxidation of sulfides to sulfoxides by hydrogen peroxide and provided 120 references, 14 tables and 16 schemes and 6 figures, with a total of 6 figures.
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Applications of Transition-Metal Catalysts to Textile and Wood-Pulp Bleaching
Ronald Hage,Achim Lienke +1 more
TL;DR: This review discusses the main classes of known bleach catalysts and their possible modes of action and offers an alternative: Transition-metal catalysts offer an alternative.
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Metal–salen complexes as efficient catalysts for the oxygenation of heteroatom containing organic compounds—synthetic and mechanistic aspects
TL;DR: In this article, a review of the metal-salen ion catalysed oxygenation of heteroatom containing organic compounds, in particular, those incorporating sulfur and nitrogen, is presented.
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Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide
TL;DR: In this paper, the use of non-heme systems for asymmetric sulfoxidation, epoxidation and dihydroxylation of alkenes has been discussed and the possibility of asymmetric oxidation catalyzed by metalloporphyrins has also been discussed.
References
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Homogeneous catalysis by transition metal oxygen anion clusters
TL;DR: In this paper, a thorough discussion of homogeneous catalysis by transition metal oxygen anion clusters (polyoxometalates), with a focus on mechanism, is provided, and a general compilation of the reactions, including catalytic electrooxidations or electroreductions, reported to date is given.
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Applications of Sulfoxides to Asymmetric Synthesis of Biologically Active Compounds
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An efficient asymmetric oxidation of sulfides to sulfoxides
TL;DR: Mise au point d'un nouveau reactif: Ti(OiC 3 H 7 ) 4 /tartrate de diethyle/eau/t-C 4 H 9 OOH dans les proportions (1:2:1:1).
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Efficient manganese catalysts for low-temperature bleaching
Ronald Hage,Jan Eric Iburg,Judith L. Kerschner,Jean Hypolites Koek,Edwin Leo M. Lempers,Rudi J. Martens,Uday S. Racherla,Stephen W. Russell,Ton Swarthoff,M. Robert P. van Vliet,Johann B. Warnaar,Lodewijk van der Wolf,Bert Krijnen +12 more
TL;DR: In this paper, it was shown that manganese complexes derived from l,4,7-trimethyl-l, 4,4-7-triazacyclononane and related ligand systems act as highly effective catalysts for the bleaching of stains by hydrogen peroxide at low temperatures.