Journal ArticleDOI
Nickel and cyclopropane reactions and photochemistry using matrix-isolation FTIR spectroscopy. Nickelacyclobutane synthesis and photofragmentation
TLDR
The reactions between atomic nickel and cyclopropane in cryogenic matrices have been investigated in this article, where the reaction was shown to form a four-membered unligated metallacycle, nickelacyclobutane, with visible photolysis induced metathesis through Ni-C and C-C bond cleavages.About:
This article is published in Organometallics.The article was published on 1988-07-01. It has received 13 citations till now. The article focuses on the topics: Metallacycle & Cyclopropane.read more
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Journal ArticleDOI
The chemistry of group 10 metalacycles
TL;DR: The metalacycles of Nickel, Palladium and Platinum in which the metal binds two carbon atoms form a rapidly growing class of compounds that find diverse applications in organic synthesis both in stoichiometric and catalytic reactions.
Journal ArticleDOI
Nanostructured nickel-clusters as catalysts in [3+2]cycloaddition reactions
TL;DR: In this paper, Ni-clusters stabilized by tetraoctyl- or tetradodecylammonium bromide are readily available by electrochemical fabrication, the average size of the particles being 2.5 nm. Colloidal solutions of such clusters effectively catalyze the cycloaddition of methylenecyclopropane to methyl acrylate.
Journal ArticleDOI
Competition between C−C and C−H Activation in Reactions of Neutral Yttrium Atoms with Cyclopropane and Propene
TL;DR: In this article, the braning ratios between C−C and C−H bond activation were measured for reactions of ground-state Y (a2D, s2d1) atoms with two C3H6 isomers (cyclopropane and propene) in crossed molecular beams.
Journal ArticleDOI
Gas Phase Atomic Hydrogen Induced Carbon−Carbon Bond Activation in Cyclopropane on the Ni(100) Surface
Kyung-Ah Son,John L. Gland +1 more
TL;DR: In this article, carbon−carbon bond activation in adsorbed cyclopropane is observed following exposure to gas phase atomic hydrogen on the Ni(100) surface for temperatures as low as 100 K.
Journal ArticleDOI
Dissociative resonance activation of cyclopropane monolayers on copper: Evidence for CH and CC bond scission
Richard Martel,Peter H. McBreen +1 more
TL;DR: In this paper, an energy selective electron beam modification of cyclopropane on Cu(110) and Cu(111) single crystal surfaces was performed using the electron beam intrinsic to a high resolution electron energy loss (HREELS) spectrometer.
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